Crystallization Behavior and Tensile Property of Poly(trimethyleneterephthalate)/Styrene-Ethylene-Buthylene-Styrene Composites

被引：1
作者：
Tsou Chi-Hui [1 ,2 ,3 ]
Suen Maw-Cherng [4 ]
Wu Wen-Yen [5 ]
Kao Bo-Jyue [6 ]
Yang Ming-Chien [6 ]
Tsou Chih-Yuan [6 ]
Hung Wei-Song [3 ]
机构：
[1] Oriental Inst Technol, Dept Mat & Text, New Taipei 22064, Taiwan
[2] Ming Chi Univ Technol, Dept Mat Engn, Ctr Thin Film Technol & Applicat, New Taipei 24301, Taiwan
[3] Chung Yuan Christian Univ, Dept Chem Engn, R&D Ctr Membrane Technol, Taoyuan 32023, Taiwan
[4] Taoyuan Innovat Inst Technol, Dept Creat Fash Design, Jhongli 32091, Taiwan
[5] Shih Chien Univ, Dept Fash Design & Merchandising, Kaohsiung 84550, Taiwan
[6] Natl Taiwan Univ Sci & Technol, Dept Mat Sci & Engn, Taipei 10607, Taiwan
来源：
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2016年 / 31卷 / 02期
关键词：
poly(trimethyleneterephthalate) (PTT); styrene-ethylene-buthylene-styrene (SEBS); crystallization; POLY(TRIMETHYLENE TEREPHTHALATE); CHAIN EXTENDER; NANOCOMPOSITES; BLENDS; THERMOPLASTICS; DEFORMATION; POLYAMIDES;
D O I：
10.1007/s11595-016-1394-8
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Poly(trimethyleneterephthalate) (PTT)/styrene-ethylene-buthylene-styrene (SEBS) composites were prepared by melt compounding. Polarizing optical microscopy was used to observe the spherulitic morphology and the crystal structure of PTT and PTT/SEBS composites. Scanning electron microscopy was used to determine the dispersion and the compatibility of fracture surfaces of PTT and SEBS. The curves of thermal gravimetric analysis illustrated that the thermo stability decreased with increasing SEBS content. Differential scanning calorimetry was used to investigate the crystallization behavior; and the result showed that the glass transition temperature of the compound increased with the SEBS content. The Avrami equation described the isothermal crystallization kinetics. Stress-strain curves for PTT and PTT/SEBS composites showed that the elongation at break was enhanced with increasing SEBS content.
引用
收藏
页码：474 / 480
页数：7
相关论文
共 26 条
[1]   Kinetics of phase change I - General theory [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112
[2]   Orientation and structure development in poly(trimethylene terephthalate) tensile drawing [J].
Chuah, HH .
MACROMOLECULES, 2001, 34 (20) :6985-6993
[3]   Thermal, crystallization, and rheological characteristics of poly (trimethylene terephthalate)/poly(butylene terephthalate) blends [J].
Dangseeyun, N ;
Supaphol, P ;
Nithitanakul, M .
POLYMER TESTING, 2004, 23 (02) :187-194
[4]   Deformation of undrawn poly(trimethylene terephthalate) (PTT) fibers [J].
Grebowicz, JS ;
Brown, H ;
Chuah, H ;
Olvera, JM ;
Wasiak, A ;
Sajkiewicz, P ;
Ziabicki, A .
POLYMER, 2001, 42 (16) :7153-7160
[5]   A novel polymeric ionomer as a potential biomaterial: Crystallization behavior, degradation, and in-vitro cellular interactions [J].
Han, SI ;
Kang, SW ;
Kim, BS ;
Im, SS .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (03) :367-374
[6]   Banded Spherulites Grown from Poly(trimethylene terephthalate) Solution-cast Film [J].
He Xingquan ;
Yang Decai .
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2008, 23 (06) :791-794
[7]   Improvement of thermal inertia of styrene-ethylene/butylene-styrene (SEBS) polymers by addition of microencapsulated phase change materials (PCMs) [J].
Juarez, D. ;
Ferrand, S. ;
Fenollar, O. ;
Fombuena, V. ;
Balart, R. .
EUROPEAN POLYMER JOURNAL, 2011, 47 (02) :153-161
[8]   Co-continuous polyamide 6 (PA6)/acrylonitrile-cutadiene-styrene (ABS) nanocomposites [J].
Li, YJ ;
Shimizu, H .
MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (09) :710-715
[9]  
OSHINSKI AJ, 1992, POLYMER, V33, P268, DOI 10.1016/0032-3861(92)90984-5
[10]   Positron annihilation and differential scanning calorimetric study of poly(trimethylene terephthalate)/EPDM blends [J].
Ravikumar, HB ;
Ranganathaiah, C ;
Kumaraswamy, GN ;
Thomas, S .
POLYMER, 2005, 46 (07) :2372-2380
123