A family of ferrocene-rich Mn7, Mn8 and Mn13 clusters

被引：24
作者：
Masello, Antonio [1 ]
Murugesu, Muralee [1 ]
Abboud, Khalil A. [1 ]
Christou, George [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
来源：
POLYHEDRON | 2007年 / 26卷 / 9-11期
基金：
美国国家科学基金会;
关键词：
manganese; clusters; crystal structures; mixed valence; 1,1 '-ferrocenedicarboxylate;
D O I：
10.1016/j.poly.2006.11.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The use of ferrocene-1,1'-dicarboxylic acid (fdcH(2)) in Mn cluster chemistry has led to a family of ferrocene-rich Mn-7, Mn-8 and Mn-13 clusters. The complexes are all mixed-valence. Solid-state DC and AC magnetic susceptibility studies have established the Mn-7, Mn-8 and Mn-13 complexes to possess S = 2, 5 and 9/2 ground states, respectively. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2276 / 2280
页数：5
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