The effect of sintering temperature on porous silica composite strength

被引:20
作者
Han, YS [1 ]
Li, JB [1 ]
Chi, B [1 ]
Wen, ZH [1 ]
机构
[1] Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
关键词
resin-impregnated method; silica; clay; strength; sintering temperature;
D O I
10.1023/A:1024070114030
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The effect of sintering temperature on porous silica composite strength was studied by discussing three factors, namely crystal phase, glassy phase and porosity. The fired products of clay and silica are composed of crystalline phase and glassy phase. The crystalline phases consist of alpha-quartz and mullite and the glassy phase contains a disordered silica network. With the increase of sintering temperature up to 1360degreesC, the crystalline silica decreased gradually. The disappearing silica dissolved into the glass and became a part of glass network and resulted in the enhancement of glass strength. This change in glass played an important role in the improvement of sample strength. At the same time, the increase of sintering temperature promoted the densification of samples and reduced the porosity of products, which also contribute to the increase of sample strength. When the sintering temperature is up to 1390degreesC, the silica in glass tended to convert to cristobalite with the expansion of glassy phase. This expansion weakened the connection of atoms in glass network and brought some closed pores into products, which led to the decrease of sample strength.
引用
收藏
页码:41 / 45
页数:5
相关论文
共 11 条
[1]   Fabrication and characterisation of Al2O3 porous bodies by hot isostatic pressing [J].
Biasini, V ;
Parasporo, M ;
Bellosi, A .
THIN SOLID FILMS, 1997, 297 (1-2) :207-211
[2]  
Brockmeyer J.W., 1982, U.S. Patent, Patent No. [4 343 704, 4343704]
[3]   Studies on the control of porous properties in the fabrication of porous supports [J].
Chao, WJ ;
Chou, KS .
POROUS CERAMIC MATERIALS, 1996, 115 :93-108
[4]  
Davis JB, 2000, J AM CERAM SOC, V83, P2369, DOI 10.1111/j.1151-2916.2000.tb01563.x
[5]  
FANDERLIK I, 1991, SILICA GLASS ITS APP, P147
[6]   The effect of sintering temperatures on alumina foam strength [J].
Han, YS ;
Li, JB ;
Wei, QM ;
Tang, K .
CERAMICS INTERNATIONAL, 2002, 28 (07) :755-759
[7]  
Hargus P, 1989, U.S. Patent, Patent No. [4 866 011, 4866011]
[8]   SYNTHESIS AND CHARACTERIZATION OF AL2O3 CATALYST CARRIERS BY SOL-GEL [J].
SIMON, C ;
BREDESEN, R ;
GRONDAL, H ;
HUSTOFT, AG ;
TANGSTAD, E .
JOURNAL OF MATERIALS SCIENCE, 1995, 30 (21) :5554-5560
[9]  
SOSMAN RB, 1994, PHASE SILICA, P34
[10]  
Yang SM, 2000, ADV MATER, V12, P1940, DOI 10.1002/1521-4095(200012)12:24<1940::AID-ADMA1940>3.0.CO