A heme-like, water-soluble iron(II) porphyrin:: thermal and photoinduced properties, evidence for sitting-atop structure

被引:30
作者
Huszánk, R [1 ]
Horváth, O [1 ]
机构
[1] Univ Veszprem, Dept Gen & Inorgan Chem, H-8200 Veszprem, Hungary
关键词
D O I
10.1039/b414673e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Water-soluble ferrous porphyrin ((FeTPPS)-T-II) was prepared by complexation reaction of free base porphyrin (H2TPPS) with iron(II) ions in the presence of iron(III)-trapping acetate buffer; the catalytic and photoinduced properties of this air-stable complex proved unambiguously its sitting-atop structure.
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页码:224 / 226
页数:3
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