Light-Regulated Molecular Trafficking in a Synthetic Water-Soluble Host

被引：68

作者：

del Barrio, Jesus ^{[1
,2
]}

Ryan, Sean T. J. ^{[1
]}

Jambrina, Pablo G. ^{[3
]}

Rosta, Edina ^{[3
]}

Scherman, Oren A. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Lensfield Rd, Cambridge CB2 1EW, England

[2] Schlumberger Gould Res, Madingley Rd, Cambridge CB3 0EL, England

[3] Kings Coll London, Dept Chem, London SE1 1DB, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 18期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

BINDING ABILITY; GUEST; RELEASE; PHOTOCONTROL; CYCLODEXTRIN; REMOTE; ENERGY;

D O I：

10.1021/jacs.5b11642

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cucurbit[8]uril (CB [8])-mediated cornplexation of a dicationic azobenzene in water allows for the light-controlled encapsulation of a variety of second guest compounds, including amino acids, dyes, and fragrance molecules. Such controlled guest sequestration inside the cavity of CB [8] enables the regulation of the thermally induced phase transition of poly(N-isopropylacrylamide) which is not photosensitive thus demonstrating the robustness and relevancy of the light-regulated CB [8] complexation.

引用

页码：5745 / 5748

页数：4

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