Reaction of carbon tetrachloride with hydrogen peroxide

被引：9

作者：

Tatarova, LA ^{[1
]}

Trofimova, KS ^{[1
]}

Gorban, AV ^{[1
]}

Khaliullin, AK ^{[1
]}

机构：

[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Div, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 40卷 / 10期

关键词：

Hydrogen; Iron; Chloride; Experimental Data; Hydrogen Peroxide;

D O I：

10.1007/s11178-005-0031-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of carbon tetrachloride with aqueous hydrogen peroxide in the presence of anhydrous iron(III) chloride was studied. Optimal conditions for the preparation of phosgene were found on the basis of analysis of the kinetic data and mechanism of the process. The reaction rate and yield (the latter reaching 95% in the stationary mode) are determined mainly by the amount of the heterogeneous catalyst. According to the experimental data, the reaction follows a radical mechanism.

引用

页码：1403 / 1406

页数：4