Accelerated FeIII/FeII redox cycle of Fenton reaction system using Pd/NH2-MIL-101(Cr) and hydrogen

被引：7
作者：
Liu, Zhong-Xing [1 ]
Liu, Xin [1 ,2 ]
Li, Yong [1 ]
Gao, Shi-Qian [1 ]
机构：
[1] Suzhou Univ Sci & Technol, Inst Environm Protect Applicat Technol, Sch Environm Sci & Engn, Tianping Coll, Suzhou, Jiangsu, Peoples R China
[2] Suzhou Mengli Environm Technol Co Ltd, Suzhou, Jiangsu, Peoples R China
来源：
TURKISH JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 02期
关键词：
Fenton reaction; accelerated reduction of Fe-III; hydrogen; palladium; NH2-MIL-101(Cr); METAL-ORGANIC FRAMEWORKS; PALLADIUM NANOPARTICLES; OXIDATION; DEGRADATION; CATALYST; IRON; TEMPERATURE; GENERATION; REMOVAL; IONS;
D O I：
10.3906/kim-2008-34
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper, a novel improvement in the catalytic Fenton reaction system named MHACF-NH2-MIL-101(Cr) was constructed based on H-2 and Pd/NH2-MIL-101(Cr). The improved system would result in an accelerated reduction in Fe-III, and provide a continuous and fast degradation efficiency of the 10 mg L-1 4-chlorophenol which was the model contaminant by using only trace level Fe-II. The activity of Pd/NH2-MIL-101(Cr) decreased from 100% to about 35% gradually during the six consecutive reaction cycles of 18 h. That could be attributed to the irreversible structural damage of NH2-MIL-101(Cr).
引用
收藏
页码：377 / +
页数：19
相关论文
共 50 条
[11]   The synthesis of mesostructured NH2-MIL-101(Cr) and kinetic and thermodynamic study in tetracycline aqueous solutions [J].
Tian, Na ;
Jia, QingMing ;
Su, HongYing ;
Zhi, YunFei ;
Ma, AiHua ;
Wu, Jing ;
Shan, ShaoYun .
JOURNAL OF POROUS MATERIALS, 2016, 23 (05) :1269-1278
[12]   Mesoporous metal-organic framework NH2-MIL-101(Cr) as an efficient photocatalyst for the epoxidation of styrene [J].
Wang, Xue-Zhi ;
Cai, Bing-Chen ;
Zhou, Yi-Jie ;
Zhou, Chuang-Wei ;
Wu, Ming-Min ;
Zhou, Xian-Chao ;
Wang, Fu-Li ;
Zhou, Xiao-Ping ;
Li, Dan .
DALTON TRANSACTIONS, 2024, 53 (36) :15297-15304
[13]   CaO nanoparticles incorporated metal organic framework (NH2-MIL-101) for Knoevenagel condensation reaction [J].
Aljaddua, Huda, I ;
Alhumaimess, Mosaed S. ;
Hassan, Hassan M. A. .
ARABIAN JOURNAL OF CHEMISTRY, 2022, 15 (02)
[14]   Effective flocculation of harmful algae Microcystis aeruginosa by nanoscale metal-organic framework NH2-MIL-101(Cr) [J].
Li, Yiling ;
Xu, Zhengtao ;
Wang, Wen-Xiong .
CHEMICAL ENGINEERING JOURNAL, 2022, 433
[15]   Sustainable Catalysis: Rational Pd Loading on MIL-101Cr-NH2 for More Efficient and Recyclable Suzuki-Miyaura Reactions [J].
Pascanu, Vlad ;
Yao, Qingxia ;
Gomez, Antonio Bermejo ;
Gustafsson, Mikaela ;
Yun, Yifeng ;
Wan, Wei ;
Samain, Louise ;
Zou, Xiaodong ;
Martin-Matute, Belen .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (51) :17483-17493
[16]   Influence of the Base on Pd@MIL-101-NH2(Cr) as Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction [J].
Carson, Fabian ;
Pascanu, Vlad ;
Gomez, Antonio Bermejo ;
Zhang, Yi ;
Platero-Prats, Ana E. ;
Zou, Xiaodong ;
Martin-Matute, Belen .
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (30) :10896-10902
[17]   NH2-MIL-101(Fe)-mediated photo-Fenton reaction enhanced simultaneous removal of nitrogen and refractory organics in anammox process through interfacial electron transfer [J].
Si, Guangchao ;
Yang, Jiachun ;
Zhang, Li ;
Gao, Jingfeng ;
Zhang, Shujun ;
Ni, Shouqing ;
Peng, Yongzhen .
BIORESOURCE TECHNOLOGY, 2024, 395
[18]   Facile synthesis of nanometer-sized NH2-MIL-101(Fe) decorated BiOBr hybrids for efficient Cr(VI) photoreduction [J].
Chen, Feng ;
Wang, Huihu ;
Tu, Hao ;
Xu, Huang ;
Zhang, Ziguan ;
Chen, Guode ;
Wei, Chenhuinan ;
Xiang, Xing ;
Xie, Zhixiong .
JOURNAL OF SOLID STATE CHEMISTRY, 2024, 329
[19]   Cooperation of oxygen vacancy and FeIII/FeII sites in H2-reduced Fe-MIL-101 for enhanced Fenton-like degradation of organic pollutants [J].
Bao, Chaosheng ;
Wang, Hu ;
Wang, Caiyun ;
Zhang, Xiaohui ;
Zhao, Xiaoliang ;
Dong, Chung-Li ;
Huang, Yu-Cheng ;
Chen, Shuai ;
Guo, Peng ;
She, Xilin ;
Sun, Yuanyuan ;
Yang, Dongjiang .
JOURNAL OF HAZARDOUS MATERIALS, 2023, 441
[20]   Adsorption behavior and mechanism of NH2-MIL-101(Cr)@COFs@SA composite adsorbent for tetracycline removal [J].
Zhang, Shaopeng ;
Ding, Jie ;
Tian, Dayong ;
Su, Wenhui ;
Liu, Chao ;
Zhang, Jiale ;
Xie, Haijiao ;
Lu, Minghua .
POLYMER, 2024, 312
12345