Structure and magnetic properties of iron oxide films deposited by excimer laser ablation of a metal-containing polymer

被引:23
|
作者
Ouyang, M
Hiraoka, H
机构
[1] Department of Chemistry, Hong Kong Univ. of Sci. and Technol., Kowloon, Clear Water Bay
关键词
magnetic materials; thin films; polymers; laser deposition;
D O I
10.1016/S0025-5408(97)00079-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The process of depositing iron oxide films on fused quartz substrates via the plume generated by excimer laser ablation of poly(ferric methacrylate), a metal-containing polymer, is reported in this paper. The chemical composition of the deposited films was analyzed by means of X-ray photoelectron spectroscopy and Raman spectroscopy. The results suggest that the deposited films consist of iron-rich Fe3O4 and alpha-Fe2O3. The microcrystalline structures of Fe3O4 and alpha-Fe2O3 in the deposited films were revealed by X-ray diffraction. The morphology of the deposited films presents ball-like grains with nanometer-size structure, which was observed by scanning electron microscopy. The measurements of magnetic properties of the deposited films show that they are ferromagnetic. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:1099 / 1107
页数:9
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