Ordovician K-bentonites in the upper-plate active margin of Western Gondwana, (Famatina Ranges): Stratigraphic and palaeogeo graphic significance

Numerous, thin-bedded, tabular pale-yellowish clay hands are interlayered with black shales in a biostratigraphically constrained Early Ordovician volcano-sedimentary succession at Famatina, western Argentina. This region was part of a fairly continuous upper-plate, convergent volcanic chain that fringed western Gondwana. Mineralogy on both clay and non-clay fractions, whole rock chemistry and field observations on these distinctive event-beds indicate that they originated as relatively coarse fallout tephras, altered first into bentonites and later, through burial metamorphism, into K-bentonites (metabentonites). These tephras were deposited as single crystals and glassy dust or pumiceous fragments in a restricted subtidal environment. The region of Famatina has previously been inferred as the source of abundant distal K-bentonites recorded in the adjacent lower-plate allochthonous Precordillera terrane. However, these K-bentonites within the proximal are site were unknown and rather unexpected since they are generally better preserved like distal deposits, associated either with central vent plinian-ultraplinian eruptions or with accompanying co-ignimbrite ash clouds. Their chemistry and comparison with those K-bentonites in the Precordillera allow tracing an evolution from volcanic arcs into continental crust. K-bentonites described in this paper are Much older than those recorded in the adjacent Precordillera terrane and seem to be associated with a first eruptive period along western Gondwana that has no counterpart in the Argentine Precordillera, suggesting a significant longitudinal separation between these two regions by the Early Ordovician. (c) 2006 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved.