A 3-D inorganic-organic hybrid framework microporous material -: Synthesis and characteristic of [CO3 (BTC) (RBTC) (H2BTC) (C2H4O2)3] • 3(DMF)-6(H3O)

被引：0

作者：

Fang, QR ^{[1
]}

Shi, X ^{[1
]}

Xin, MH ^{[1
]}

Wu, G ^{[1
]}

Tian, G ^{[1
]}

Zhu, GS ^{[1
]}

Li, YF ^{[1
]}

Ye, L ^{[1
]}

Wang, CL ^{[1
]}

Zhang, ZD ^{[1
]}

Tang, LL ^{[1
]}

Qiu, SL ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130023, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2003年 / 24卷 / 01期

关键词：

crystal structure; inorganic-organic hybrid framework; microporous material;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compound [Co-3(BTC) (HBTC) (H2BTC) (C2H4O2)(3)] . 3(DMF) . 6(H3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a = 2.645 3 ( 5) nm, b = 1.670 4 (3) nm, c = 1.821 6(4) nm, beta = 128.16(3)degrees, V = 6.329(2) nm(3), Z = 2, D-c = 20.200 Mg/m(3) M-r = 1 314.744, mu = 10.274 mm(-1), F(000) = 38 226, GOF = 0.99, R = 0.094 1, omegaR = 0.257 3.

引用

页码：28 / 30

页数：3

共 15 条

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