Plasmonic heterogeneous catalysis for organic transformations

被引：35

作者：

Zhao, Jian ^{[1
]}

Wang, Juan ^{[1
]}

Brock, Aidan J. ^{[2
]}

Zhu, Huaiyong ^{[2
]}

机构：

[1] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin Key Lab Organ Solar Cells & Photochem Conv, Tianjin 300384, Peoples R China

[2] Queensland Univ Technol, Ctr Mat Sci, Sch Chem & Phys, 2 George St, Brisbane, Qld 4000, Australia

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS | 2022年 / 52卷

基金：

中国国家自然科学基金;

关键词：

Localized surface plasmon resonance; Organic transformations; Plasmonic heterogeneous catalysis; Visible light; Control of selectivity; SUPPORTED GOLD NANOPARTICLES; SELECTIVE AEROBIC OXIDATION; VISIBLE-LIGHT IRRADIATION; BIMETALLIC ALLOY NANOPARTICLES; MIYAURA COUPLING REACTION; METAL NANOPARTICLES; HIGHLY EFFICIENT; PHOTOCATALYTIC OXIDATION; SILVER NANOPARTICLES; OPTICAL-PROPERTIES;

D O I：

10.1016/j.jphotochemrev.2022.100539

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Plasmonic catalysis has been recognised as a promising alternative to many conventional thermal catalytic processes in organic synthesis. In addition to their high activity in fine chemical synthesis, plasmonic photo -catalysts are also able to maintain control of selectivity under mild conditions by utilising visible-light as an energy source. This review provides an overview of the recent advances in organic transformations with plas-monic metal nanostructures, including selective reduction, selective oxidation, cross-coupling and addition re-actions. We also summarize the photocatalysts and catalytic mechanisms involving surface plasmon resonance. Finally, control of reaction pathway and strategies for tailoring product selectivity in fine chemical synthesis are discussed.

引用

页数：28

共 208 条

[1] Plasmonic oxidation of glycerol using AuPd/TiO2 catalysts [J].