A polychromic, fast response metallopolymer gel photonic crystal with solvent and redox tunability:: A step towards photonic ink (P-Ink)

被引:195
作者
Arsenault, AC [1 ]
Míguez, H [1 ]
Kitaev, V [1 ]
Ozin, GA [1 ]
Manners, I [1 ]
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
关键词
D O I
10.1002/adma.200390116
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A conceptually new approach to the fabrication of rapid-response chemomechanical colloidal photonic crystal device with redox and solvent tunability based on the anisotropic expansion of the cross-linked PFSmatrix surrounding a closed-packed array of unconnected silica spheres was demonstrated. The samples were planarized and oriented, have high structural and optical quality. Moreover, it presents a very low defect concentration, portending the use of this system in future optical communication systems and electro-photonic displays.
引用
收藏
页码:503 / 507
页数:5
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