Catalytic Aerobic Oxidation of Biomass-based Furfural into Maleic Acid in Aqueous Phase with Metalloporphyrin Catalysts

被引：26

作者：

Huang, Yi ^{[1
]}

Wu, Chunyan ^{[1
]}

Yuan, Wenwen ^{[1
]}

Xia, Yongmei ^{[2
]}

Liu, Xiang ^{[1
]}

Yang, Huamei ^{[3
]}

Wang, Haijun ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Peoples R China

[2] State Key Lab Food Sci & Technol, Wuxi 214122, Peoples R China

[3] Xuzhou Univ Technol, Sch Chem & Chem Engn, Xuzhou 221000, Peoples R China

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2017年 / 64卷 / 07期

关键词：

Furfural; Biomass catalytic conversion; Metalloporphyrins; Maleic acid; N-BUTANE OXIDATION; 2,5-FURANDICARBOXYLIC ACID; PORPHYRIN COMPLEX; DERIVATIVES; ANHYDRIDE; CLEAVAGE; H2O2;

D O I：

10.1002/jccs.201700004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic oxidation of renewable furfural into valuable maleic acid in aqueous solutions using metalloporphyrin catalysts was investigated for the first time. The synthesized catalysts were characterized by FT-IR, UV-vis, H-1 NMR, elemental analysis, and TGA. The catalysts varied in metal active sites and functional groups, which had different effects on their catalytic activity. Furthermore, the effects of temperatures, reaction time, catalyst loading, and oxygen pressure were studied in detail. Maleic acid could be achieved in 44% yield by using FeT(p-Cl)PPCl as catalyst under optimal conditions. Finally, FeT(p-Cl)PPCl could be reused in five consecutive runs without a significant loss of activity.

引用

页码：786 / 794

页数：9

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