Crystal engineering strategy for quadratic nonlinear optics.: Part II:: Hg(IO3)2

被引：36

作者：

Bentria, B

Benbertal, D

Bagieu-Beucher, M

Mosset, A

Zaccaro, J

机构：

[1] Univ Grenoble 1, Lab Cristallog, CNRS, F-38042 Grenoble 9, France

[2] Univ Laghouat, Lab Sci Fondamentales, Laghouat 03000, Algeria

来源：

SOLID STATE SCIENCES | 2003年 / 5卷 / 02期

关键词：

D O I：

10.1016/S1293-2558(03)00004-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The noncentrosymmetric material Hg(IO3)(2) with P2(1) space group symmetry has been synthesised. This compound is thermally very stable (520 degreesC) and shows a NLO efficiency visually comparable to that of lithium iodate. The crystal structure has been solved in order to relate this efficiency to the IO3 chomophore packing. Simple calculations, based on the bond additivity model, show that both I-I and Hg-O bonds contribute to SHG tensor. (C) 2003 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

引用

页码：359 / 365

页数：7

共 45 条

[1] TRANSITION-METAL IODATES .2. CRYSTALLOGRAPHIC, MAGNETIC, AND NONLINEAR OPTIC SURVEY OF 3D IODATES [J].