Facile synthesis of Mn-doped hollow Fe2O3 nanospheres coated with polypyrrole as anodes for high-performance lithium-ion batteries

被引:10
作者
Li, Guangda [1 ]
Han, Rumeng [1 ]
Xu, Xiaoyun [1 ]
Ren, Manman [1 ]
机构
[1] Qilu Univ Technol, Sch Mat Sci & Engn, Key Lab Proc & Testing Technol Glass & Funct Cera, Jinan 250353, Peoples R China
基金
中国国家自然科学基金;
关键词
ELECTROCHEMICAL PERFORMANCE; CARBON MICROSPHERES; POTENTIAL ANODE; COMPOSITE; NANOSTRUCTURES; NANOPARTICLES; FABRICATION; MICROCUBES; NANORODS; DESIGN;
D O I
10.1039/c6ra08740j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mn-doped Fe2O3/PPy hollow composite nanospheres were fabricated by a facile solvothermal method. The Mn-Fe2O3/PPy electrode showed an improved electrochemical performance in terms of high rate capability and long cycling performance compared with Fe2O3 without Mn doping and PPy coating. At current densities of 500 mA g(-1) and 1000 mA g(-1), the Mn-Fe2O3/PPy exhibited an initial capacity of 1214.7 and 924.9 mA h g(-1), and the capacity was maintained at 795.7 and 643.6 mA h g(-1) after 200 cycles.
引用
收藏
页码:48199 / 48204
页数:6
相关论文
共 37 条
[1]   Design and evaluation of novel Zn doped mesoporous TiO2 based anode material for advanced lithium ion batteries [J].
Ali, Zahid ;
Cha, Seung Nam ;
Sohn, Jung Inn ;
Shakir, Imran ;
Yan, Changzeng ;
Kim, Jong Min ;
Kang, Dae Joon .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (34) :17625-17629
[2]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[3]   Design and synthesis of micron-sized spherical aggregates composed of hollow Fe2O3 nanospheres for use in lithium-ion batteries [J].
Cho, Jung Sang ;
Hong, Young Jun ;
Lee, Jong-Heun ;
Kang, Yun Chan .
NANOSCALE, 2015, 7 (18) :8361-8367
[4]   Self-assembled three-dimensional mesoporous ZnFe2O4-graphene composites for lithium ion batteries with significantly enhanced rate capability and cycling stability [J].
Dong, Yucheng ;
Xia, Yang ;
Chui, Ying-San ;
Cao, Chenwei ;
Zapien, Juan Antonio .
JOURNAL OF POWER SOURCES, 2015, 275 :769-776
[5]   Conducting polymer/carbon particle thermoelectric composites: Emerging green energy materials [J].
Gao, Caiyan ;
Chen, Guangming .
COMPOSITES SCIENCE AND TECHNOLOGY, 2016, 124 :52-70
[6]   Gelatin-based carbon microspheres with a foam-like core/solid shell structure [J].
Ge, Jun ;
Shi, Jingjing ;
Chen, Lijuan .
CARBON, 2009, 47 (04) :1192-1195
[7]   One-step synthesis of highly aligned SnO2 nanorods on a self-produced Na2Sn(OH)6 substrate for high-performance lithium-ion batteries [J].
Han, Xiguang ;
Han, Xiao ;
Sun, Linqiang ;
Liu, Qianqian ;
Xu, Wei ;
Li, Liang ;
Wang, Po ;
Wang, Chao .
CRYSTENGCOMM, 2015, 17 (08) :1754-1757
[8]   Self-Sacrifice Template Fabrication of Hierarchical Mesoporous Bi-Component-Active ZnO/ZnFe2O4 Sub-Microcubes as Superior Anode Towards High-Performance Lithium-Ion Battery [J].
Hou, Linrui ;
Lian, Lin ;
Zhang, Longhai ;
Pang, Gang ;
Yuan, Changzhou ;
Zhang, Xiaogang .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (02) :238-246
[9]   Hierarchical Hollow Spheres of Fe2O3@Polyaniline for Lithium Ion Battery Anodes [J].
Jeong, Jae-Min ;
Choi, Bong Gill ;
Lee, Soon Chang ;
Lee, Kyoung G. ;
Chang, Sung-Jin ;
Han, Young-Kyu ;
Lee, Young Boo ;
Lee, Hyun Uk ;
Kwon, Soonjo ;
Lee, Gaehang ;
Lee, Chang-Soo ;
Huh, Yun Suk .
ADVANCED MATERIALS, 2013, 25 (43) :6250-6255
[10]   Ni2+ ion assisted synthesis of hexagonal α-Fe2O3 nanoplates as anode materials for lithium-ion batteries [J].
Jin, Rencheng ;
Yang, Lixia ;
Li, Guihua ;
Chen, Gang .
NEW JOURNAL OF CHEMISTRY, 2014, 38 (12) :5840-5845