Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdo(V,VI)phosphate hexahydrate

被引：2

作者：

Hao, Lujiang ^{[1
]}

Liu, Tongjun ^{[1
]}

Chen, Jiangkui ^{[1
]}

Zhang, Xiaofei ^{[1
]}

机构：

[1] Shandong Inst Light Ind, Coll Food & Biol Engn, Jinan 250353, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

CRYSTAL-STRUCTURE;

D O I：

10.1107/S1600536810005945

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The hydrothermally prepared title compound, [Ni(C8H7N3)(3)](2)[PMo12O40]center dot 6H(2)O, is a member of the isotypic series [(M(C8H7N3)(3)](2)[PMo12O40]center dot 6H(2)O where M is Mn, Cd, and Fe. The Ni2+ cation is in a distorted octahedral environment, coordinated by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands. In the one-electron reduced heteropolyanion, two O atoms of the central PO4 group (1 symmetry) are equally disordered about an inversion centre. N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds contribute to the crystal packing. Compared with the isotypic structures, the main difference is related with the M-N bond lengths, whereas all other bond lengths, angles and the hydrogenbonding motifs are very similar.

引用

页码：M319 / U3730

页数：17