Three-dimensional microporous metal-organic framework constructed from Cadmium(II) ion with terephthalate and in-situ generated amino-tetrazole mixed-ligands

被引：16
|
作者：
Liu, DongSheng [1 ,2 ,3 ]
Sui, Yan [2 ,3 ]
Huang, ChangCang [1 ]
Pan, TongHen [1 ]
Huang, XiHe [1 ]
Chen, JianZhong [1 ]
You, XiaoZeng [3 ]
机构：
[1] Fuzhou Univ, Coll Chem & Chem Engn, State Key Lab Breeding Base Photocatalysis, Fuzhou 350108, Fujian, Peoples R China
[2] Jinggangshan Univ, Coll Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China
[3] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 06期
关键词：
5-Amino-tetrazolate; In-situ; Mixed-ligand; Topology; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SPIN-CROSSOVER; HYDROTHERMAL SYNTHESIS; LUMINESCENT PROPERTIES; ZINC; COMPLEXES; CHEMISTRY; COPPER(II); DIFFRACTION;
D O I：
10.1016/j.inoche.2010.03.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer, [Cd-4(atz)(6)(PTA)](n) has been firstly synthesized by employing mixed-ligand of terephthalic acid (PTA) with the in-situ generated ligand of 5-amino-tetrazolate (atz(-)). Compound 1 represents a 3D microporous framework constructed from Cd-tetrazolate subunits and the subunits are bridged by PTA and atz ligands. When the subunit was collided into node, compound 1 possesses an unprecedented 3, 9-connected topological network. Furthermore, the investigations of thermal stability and luminescent property of complex 1 indicate that compound 1 may be an excellent candidate for potential blue-light emitting material. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：762 / 765
页数：4
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