A solid nickel(II) complex with methionine sulfoxide

被引：13

作者：

Corbi, PP

Melnikov, P

Massabni, AC

机构：

[1] UNESP, Inst Chem, Dept Gen & Inorgan Chem, BR-14801970 Araraquara, SP, Brazil

[2] Univ Fed Mato Grosso do Sul, CCET, BR-79070900 Campo Grande, MS, Brazil

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2000年 / 308卷

基金：

巴西圣保罗研究基金会;

关键词：

bioinorganic chemistry; methionine sulfoxide; amino acids; nickel(II);

D O I：

10.1016/S0925-8388(00)01022-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solid Ni(C5H10NO3S)(2) . 2H(2)O complex was prepared and characterized. Electronic absorption spectrum shows an octahedral geometry for the complex. Infrared spectroscopy analysis shows that the metal atom is coordinated to the ligand through (COO-) and (S = O) groups. Thermal analysis confirmed the composition of the complex and suggests that the water molecules are not coordinated to the metal ion. The complex shows extremely high solubility in water. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：153 / 157

页数：5

共 20 条

[1] CARROT FLAVOR - SUGARS AND FREE NITROGENOUS COMPOUNDS IN FRESH CARROTS [J].