High performance and stability of double perovskite-type oxide NdBa0.5Ca0.5Co1.5Fe0.5O5+δ as an oxygen electrode for reversible solid oxide electrochemical cell

In this study, we successfully synthesized double perovskite-type oxide NdBa0.5Ca0.5Co1.5Fe0.5O5+delta (NBCCF) using a conventional wet chemical method as the oxygen electrode for reversible solid oxide electrochemical cells (RSOCs). The polarization resistance (R-p) of the composite electrode NBCCF-Gd0.1Ce0.9O2 (GDC) is only 0.079 Omega cm(2) at 800 degrees C under air. The single cell based on NBCCF-GDC electrode displays a peak power density of 0.941 W/cm(2) in fuel cell mode and a low R-p value of 0.134 Omega cm(2). In electrolysis cell mode, the cell displays an outstanding oxygen evolution reaction (OER) activity and shows current density as high as 0.92 A/cm(2) with 50 vol% AH (Absolute Humidity) at 800 degrees C and applied voltage of 1.3 V. Most importantly, the cell exhibits admirable durability of 60 h both in electrolysis mode and fuel cell mode with distinguished reversibility. All these results suggest that NBCCF is a promising candidate electrode for RSOC. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.