The synthesis, crystal structure and spectroscopic properties of a new two-dimensional silver(I) coordination network

被引：23

作者：

Fei, BL

Sun, WY ^{[1
]}

Zhang, YA

Yu, KB

Tang, WX

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Chinese Acad Sci, Anal Ctr, Chengdu 610041, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2000年 / 306卷 / 01期

关键词：

crystal structures; silver complexes; tetradentate ligand complexes; hydrogen bonds;

D O I：

10.1016/S0020-1693(00)00143-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A flexible tetradentate ligand 1,6-bis(4'-pyridyl)-2,5-diazahexane (BPDH) reacts with tetrakis(acetonitrile)silver(I) tetrafluoroborate to form a novel two-dimensional network complex [Ag(BPDH)]BF(4). CH(3)CN. The compound crystallizes in monoclinic, space group P2(1)/n with a = 14.121(2), b = 7.0410(10), c = 19.803(3) Angstrom, beta = 94.700(10)degrees, V = 1962.3(5) Angstrom(3) and Z = 4. The solvate acetonitrile molecule and counter anions are incorporated in the channels formed between two adjacent sheets through C-H ... F, N-H ... F and N-H ... N hydrogen bonds. The spectroscopic properties of the complex as luminescent, thermogravimetric and electrospray mass spectrometry were also described. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：106 / 111

页数：6

共 35 条

[1] A NEW TYPE OF INFINITE 3D POLYMERIC NETWORK CONTAINING 4-CONNECTED, PERIPHERALLY LINKED METALLOPORPHYRIN BUILDING-BLOCKS [J].