High-Turnover Photochemical Hydrogen Production Catalyzed by a Model Complex of the [FeFe]-Hydrogenase Active Site

被引：182

作者：

Streich, Daniel ^{[1
]}

Astuti, Yeni ^{[1
]}

Orlandi, Michele ^{[2
]}

Schwartz, Lennart ^{[1
]}

Lomoth, Reiner ^{[1
]}

Hammarstrom, Leif ^{[1
]}

Ott, Sascha ^{[1
]}

机构：

[1] Uppsala Univ, Dept Photochem & Mol Sci, S-75120 Uppsala, Sweden

[2] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 01期

关键词：

homogeneous catalysis; hydrogen; hydrogenase models; iron; photochemistry; VISIBLE-LIGHT; HOMOGENEOUS SYSTEM; MOLECULAR-HYDROGEN; WATER; GENERATION; EVOLUTION; PHOTOGENERATION; PHOTOCATALYST; REDUCTION; ELECTRON;

D O I：

10.1002/chem.200902489

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

"Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：60 / 63

页数：4

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