Molecular structure and magnetic properties of N,N-bis{4-methoxy-3,5-bis(N-tert-butyl-N-oxyamino)phenyl)}aminoxyl.: An approach to a stable and high-spin pentaradical

被引：13

作者：

Fujita, J

Matsuoka, Y

Matsuo, K

Tanaka, M

Akita, T

Koga, N ^{[1
]}

Iwamura, H

机构：

[1] Kyushu Univ, Fac Pharmaceut Sci, Fukuoka 81282, Japan

[2] Kyushu Univ, Inst Fundamental Res Organ Chem, Fukuoka 81282, Japan

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 24期

关键词：

D O I：

10.1039/a704160h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stable pentaradical, N,N-bis{4-methoxy-3,5-bis(N-tert-butyl-N-oxyamino)phenyl)}aminoxyl, is prepared and its ground state determined to be a sextet(S = 5/2) by SQUID magnetization measurements of the pentaradical diluted in poly(vinyl chloride) matrix.

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页码：2393 / 2394

页数：2

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