Low temperature synthesis of visible light-driven vanadium doped titania photocatalyst

被引:40
作者
Li, Hong [2 ]
Zhao, Gaoling [2 ]
Chen, Zhijun [2 ]
Han, Gaorong [2 ]
Song, Bin [1 ]
机构
[1] Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
基金
中国国家自然科学基金;
关键词
Photocatalyst; Low temperature; TiO2; Sol-gel; SOL-GEL METHOD; NANOCRYSTALLINE TIO2; FILMS; IRRADIATION;
D O I
10.1016/j.jcis.2010.01.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple method based on sol-gel method was developed to prepare vanadium ions doped TiO2 nanocrystalline at low temperature. Thus-obtained vanadium doped TiO2 was proved to be VxTi1-xO2 solid solution. Doping vanadium could enhance the formation of stable phase. Its optical absorption spectrum shows a red shift to 445 nm. Photodegradation experiments suggest that thus-prepared vanadium doped TiO2 nanocrystalline can be excited by visible light and is a good photocatalyst under daylight. These properties are the same as the vanadium doped TiO2 prepared under high temperature conditions (>= 350 degrees C). However, in the present work, the vanadium doped TiO2 crystal particle is very uniform and fine, about 5 nm. It is much smaller than the production prepared under high temperature. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码:247 / 250
页数:4
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