A Hollow-Structured Manganese Oxide Cathode for Stable Zn-MnO2 Batteries

被引：58

作者：

Guo, Xiaotong ^{[1
]}

Li, Jianming ^{[2
]}

Jin, Xu ^{[2
]}

Han, Yehu ^{[1
]}

Lin, Yue ^{[3
]}

Lei, Zhanwu ^{[4
]}

Wang, Shiyang ^{[4
]}

Qin, Lianjie ^{[1
]}

Jiao, Shuhong ^{[4
]}

Cao, Ruiguo ^{[4
]}

机构：

[1] Yantai Univ, Sch Environm & Mat Engn, Yantai 264005, Peoples R China

[2] PetroChina, RIPED, Beijing 100083, Peoples R China

[3] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[4] Univ Sci & Technol China, Dept Mat Sci & Engn, Key Lab Mat Energy Convers, CAS, Hefei 230026, Anhui, Peoples R China

来源：

NANOMATERIALS | 2018年 / 8卷 / 05期

基金：

中国国家自然科学基金;

关键词：

manganese oxide; hollow structure; multivalent intercalation; zinc ion batteries; DIOXIDE NANOPARTICLES; HIGH-PERFORMANCE; ZINC; INTERCALATION; BIRNESSITE;

D O I：

10.3390/nano8050301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aqueous rechargeable zinc-manganese dioxide (Zn-MnO2) batteries are considered as one of the most promising energy storage devices for large scale-energy storage systems due to their low cost, high safety, and environmental friendliness. However, only a few cathode materials have been demonstrated to achieve stable cycling for aqueous rechargeable Zn-MnO2 batteries. Here, we report a new material consisting of hollow MnO2 nanospheres, which can be used for aqueous Zn-MnO2 batteries. The hollow MnO2 nanospheres can achieve high specific capacity up to similar to 405 mAh g(-1) at 0.5 C. More importantly, the hollow structure of birnessite-type MnO2 enables long-term cycling stability for the aqueous Zn-MnO2 batteries. The excellent performance of the hollow MnO2 nanospheres should be due to their unique structural properties that enable the easy intercalation of zinc ions.

引用

页数：9

共 27 条

[1] Electrochemically Induced Structural Transformation in a γ-MnO2 Cathode of a High Capacity Zinc-Ion Battery System [J].

Alfaruqi, Muhammad H. ;

Mathew, Vinod ;

Gim, Jihyeon ;

Kim, Sungjin ;

Song, Jinju ;

Baboo, Joseph P. ;

Choi, Sun H. ;

Kim, Jaekook .

CHEMISTRY OF MATERIALS, 2015, 27 (10) :3609-3620

[2] Ambient redox synthesis of vanadium-doped manganese dioxide nanoparticles and their enhanced zinc storage properties [J].

Alfaruqi, Muhammad Hilmy ;

Islam, Saiful ;

Mathew, Vinod ;

Song, Jinju ;

Kim, Sungjin ;

Duong Pham Tung ;

Jo, Jeonggeun ;

Kim, Seokhun ;

Baboo, Joseph Paul ;

Xiu, Zhiliang ;

Kim, Jaekook .

APPLIED SURFACE SCIENCE, 2017, 404 :435-442

[3] A layered δ-MnO2 nanoflake cathode with high zinc-storage capacities for eco-friendly battery applications [J].

Alfaruqi, Muhammad Hilmy ;

Gim, Jihyeon ;

Kim, Sungjin ;

Song, Jinju ;

Duong Tung Pham ;

Jo, Jeonggeun ;

Xiu, Zhiliang ;

Mathew, Vinod ;

Kim, Jaekook .

ELECTROCHEMISTRY COMMUNICATIONS, 2015, 60 :121-125

[4] Thermodynamics of manganese oxides: Sodium, potassium, and calcium birnessite and cryptomelane [J].

Birkner, Nancy ;

Navrotsky, Alexandra .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2017, 114 (07) :E1046-E1053

[5] Molecular Storage of Mg Ions with Vanadium Oxide Nanoclusters [J].

Cheng, Yingwen ;

Shao, Yuyan ;

Raju, Vadivukarasi ;

Ji, Xiulei ;

Mehdi, B. Layla ;

Han, Kee Sung ;

Engelhard, Mark H. ;

Li, Guosheng ;

Browning, Nigel D. ;

Mueller, Karl T. ;

Liu, Jun .

ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (20) :3446-3453

[6] Highly Reversible Zinc-Ion Intercalation into Chevrel Phase Mo6S8 Nanocubes and Applications for Advanced Zinc-Ion Batteries [J].

Cheng, Yingwen ;

Luo, Langli ;

Zhong, Li ;

Chen, Junzheng ;

Li, Bin ;

Wang, Wei ;

Mao, Scott X. ;

Wang, Chongmin ;

Sprenkle, Vincent L. ;

Li, Guosheng ;

Liu, Jun .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (22) :13673-13677

[7] Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery [J].

Han, Sang-Don ;

Kim, Soojeong ;

Li, Dongguo ;

Petkov, Valeri ;

Yoo, Hyun Deog ;

Phillips, Patrick J. ;

Wang, Hao ;

Kim, Jae Jin ;

More, Karren L. ;

Key, Baris ;

Klie, Robert F. ;

Cabana, Jordi ;

Stamenkovic, Vojislav R. ;

Fister, Timothy T. ;

Markovic, Nenad M. ;

Burrell, Anthony K. ;

Tepavcevic, Sanja ;

Vaughey, John T. .

CHEMISTRY OF MATERIALS, 2017, 29 (11) :4874-4884

[8] Effect of Multiple Cation Electrolyte Mixtures on Rechargeable Zn MnO2 Alkaline Battery [J].

Hertzberg, Benjamin J. ;

Huang, An ;

Hsieh, Andrew ;

Chamoun, Mylad ;

Davies, Greg ;

Seo, Joon Kyo ;

Zhong, Zhong ;

Croft, Mark ;

Erdonmez, Can ;

Meng, Ying Shirley ;

Steingart, Dan .

CHEMISTRY OF MATERIALS, 2016, 28 (13) :4536-4545

[9] Design and Synthesis of Hierarchical MnO2 Nanospheres/Carbon Nanotubes/Conducting Polymer Ternary Composite for High Performance Electrochemical Electrodes [J].

Hou, Ye ;

Cheng, Yingwen ;

Hobson, Tyler ;

Liu, Jie .

NANO LETTERS, 2010, 10 (07) :2727-2733

[10] Highly Durable Na2V6O16•1.63H2O Nanowire Cathode for Aqueous Zinc-Ion Battery [J].

Hu, Ping ;

Zhu, Ting ;

Wang, Xuanpeng ;

Wei, Xiujuan ;

Yan, Mengyu ;

Li, Jiantao ;

Luo, Wen ;

Yang, Wei ;

Zhang, Wencui ;

Zhou, Liang ;

Zhou, Zhiqiang ;

Mai, Liqiang .

NANO LETTERS, 2018, 18 (03) :1758-1763

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