Diels-Alder [4+2]cycloaddition reactions involving C60 and C70 fullerenes

被引：0

作者：

García, MM

Klimova, E

García, RAV

Pérez, RG

机构：

[1] Univ Nacl Autonoma Mexico, Dept Quim Organ, Inst Quim, Mexico City 04510, DF, Mexico

[2] Univ Autonoma Puebla, Fac Ciencias Quim, Ctr Invest, Puebla, Pue, Mexico

来源：

REVISTA MEXICANA DE FISICA | 2000年 / 46卷

关键词：

cycloadditions; Diels-Alder; dienes; quinuclidine; chiral diimines; fullerenes;

D O I：

暂无

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

For first time dienes conjugated 8, 9 and 10 were synthesized with a s-cis conformation, and Diels-Alder cycloaddition reactions between dienes synthesized and C-60 and C-70 were carried out, and the results obtained by NMR H-1 and C-13 and elemental analysis demonstrated that the mono and biadduct compounds were formated, diene 9 was more reactive than dienes 8 and 10. Fullerenes C-60 and C-70 did not presented any difference in their reactivity like dienophiles.

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页码：126 / 131

页数：6

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