[FeIII(TF4DMAP)OTf] catalysed anti-Markovnikov oxidation of terminal aryl alkenes to aldehydes and transformation of methyl aryl tertiary amines to formamides with H2O2 as a terminal oxidant

被引：48

作者：

Du, Yi-Dan ^{[1
]}

Tse, Chun-Wai ^{[2
,3
]}

Xu, Zhen-Jiang ^{[1
]}

Liu, Yungen ^{[2
,3
]}

Che, Chi-Ming ^{[1
,2
,3
]}

机构：

[1] Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[3] Univ Hong Kong, State Key Lab Synthet Chem, Hong Kong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 84期

关键词：

WACKER-TYPE OXIDATION; MOLECULAR-OXYGEN; EPOXIDATION-ISOMERIZATION; PORPHYRIN COMPLEXES; AEROBIC OXIDATION; ORGANIC-SYNTHESIS; OLEFINS; REACTIVITY; METALLOPORPHYRIN; REARRANGEMENT;

D O I：

10.1039/c4cc05972g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anti-Markovnikov oxidation of terminal aryl alkenes to aldehydes and transformation of N-methyl aryl tertiary amines to formamides with H2O2 as a terminal oxidant under mild conditions have been achieved with moderate to good product yields using [Fe-III(TF(4)DMAP)OTf] as catalyst.

引用

页码：12669 / 12672

页数：4

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