Ferroelectric and dielectric properties of lanthanum-modified bismuth titanate thin films obtained by the polymeric precursor method

被引:15
作者
Simoes, AZ
Gonzalez, AHM
Riccardi, CS
Souza, EC
Moura, F
Zaghete, MA
Longo, E
Varela, JA [1 ]
机构
[1] Univ Estadual Paulista, UNESP, Inst Chem, BR-14801970 Araraquara, SP, Brazil
[2] Univ Fed Sao Carlos, UFSCar, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil
关键词
bismuth lanthanum titanate; FERAM; thin film;
D O I
10.1007/s10832-004-5077-z
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Lanthanum-modified bismuth titanate, Bi4-xLaxTi3O12 (BLT), thin films with a La concentration of 0.75 was grown on Pt/Ti/SiO2/Si substrates by using the polymeric precursor solution and spin-coating method. The scanning electron microscopy (SEM) showed rounded grains, which is not typical for these system. The BLT films showed well-saturated polarization-electric field curve which 2P(r) = 41.4 muC/cm(2) and V-c = 0.99 V. The capacitance dependence on the voltage is strongly nonlinear, confirming the ferroelectric properties of the film resulting from the domains switching. These properties make BLT a promising material for FERAM applications.
引用
收藏
页码:65 / 70
页数:6
相关论文
共 11 条
[1]  
Bu SD, 2000, J KOREAN PHYS SOC, V36, pL9
[2]   ELECTRICAL AND OPTICAL PROPERTIES OF FERROELECTRIC BI4TI3O12 SINGLE CRYSTALS [J].
CUMMINS, SE ;
CROSS, LE .
JOURNAL OF APPLIED PHYSICS, 1968, 39 (05) :2268-&
[3]  
Kim JP, 1999, J KOREAN PHYS SOC, V35, pS1202
[4]   PREPARATION OF C-AXIS-ORIENTED BI4TI3O-12 THIN-FILMS BY METALORGANIC CHEMICAL-VAPOR-DEPOSITION [J].
NAKAMURA, T ;
MUHAMMET, R ;
SHIMIZU, M ;
SHIOSAKI, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 (9B) :4086-4088
[5]   STRUCTURAL BASIS OF FERROELECTRICITY IN BISMUTH TITANATE FAMILY [J].
NEWNHAM, RE ;
WOLFE, RW ;
DORRIAN, JF .
MATERIALS RESEARCH BULLETIN, 1971, 6 (10) :1029-&
[6]   Structural and electrical properties of ferroelectric bismuth titanate thin films prepared by the sol gel method [J].
Sedlar, M ;
Sayer, M .
CERAMICS INTERNATIONAL, 1996, 22 (03) :241-247
[7]   FERROELECTRIC BISMUTH TITANATE FILMS BY HOT-WALL METALORGANIC CHEMICAL-VAPOR-DEPOSITION [J].
SI, J ;
DESU, SB .
JOURNAL OF APPLIED PHYSICS, 1993, 73 (11) :7910-7913
[8]  
Simoes AZ, 2002, FERROELECTRICS, V271, P1623
[9]   INTEGRATION OF FERROELECTRIC THIN-FILMS INTO NONVOLATILE MEMORIES [J].
SINHAROY, S ;
BUHAY, H ;
LAMPE, DR ;
FRANCOMBE, MH .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1992, 10 (04) :1554-1561
[10]  
WANG H, 1993, J APPL PHYS, V73, P7693