Nafion degradation mechanisms in proton exchange membrane fuel cell (PEMFC) system: A review

被引：211

作者：

Okonkwo, Paul C. ^{[1
]}

Ben Belgacem, Ikram ^{[2
]}

Emori, Wilfred ^{[3
]}

Uzoma, Paul C. ^{[4
]}

机构：

[1] Dhofar Univ, Coll Engn, Mech & Mechatron Engn Dept, Salalah, Oman

[2] Univ Monastir, Ecole Natl Ingn Monastir, Lab Genie Mecan, Monastir, Tunisia

[3] Sichuan Univ Sci & Engn, Sch Mat Sci & Engn, Zigong 643000, Sichuan, Peoples R China

[4] Fed Univ Technol Owerri, Dept Polymer & Text Engn, Owerri, Nigeria

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2021年 / 46卷 / 55期

关键词：

Nafion membrane; Degradation; Mechanism; Hydrogen; Oxygen; Electrodes; ADVANCED NANOCOMPOSITE MEMBRANES; RAY PHOTOELECTRON-SPECTROSCOPY; CHEMICAL DEGRADATION; CATALYST LAYER; PERFORMANCE DEGRADATION; COMPOSITE MEMBRANES; HYDROGEN-PEROXIDE; POLY(ETHER SULFONE); GRAPHENE OXIDE; ELECTROLYTE;

D O I：

10.1016/j.ijhydene.2021.06.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nafion is one of the polymer materials used as polymer electrode membrane (PEM) for fuel cells. However, the electrochemical reaction and water management processes that occur at the catalyst layer affect the performance and degradation of the membrane in the fuel cell resulting in various degradation mechanisms. Understanding the degradation mechanisms of the Nafion membrane in operation, the anhydrous and electrochemical conditions in the fuel cell is highly a necessity as outlined in this review. This review further recommends that further improvement in the Nafion membrane can be made by fabrication and coating the Nafion membrane with materials that can withstand the electrochemical environment in the fuel cell. (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：27956 / 27973

页数：18

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