New insights into the formation of extended supramolecular architectures from simple building blocks

被引：47

作者：

Hassaballa, H

Steed, JW

Junk, PC

机构：

[1] Kings Coll London, Dept Chem, London WC2R 2LS, England

[2] James Cook Univ N Queensland, Dept Chem, Townsville, Qld 4811, Australia

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 05期

关键词：

D O I：

10.1039/a707744k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of uranyl acetate with HCl and 15-crown-5 in toluene results in the formation of a liquid clathrate phase from which crystals of (H5O2)[UO2Cl3(H2O)(2)].(15-crown-5)(2) 1 are deposited; on standing, loss of HCl results in the isolation of a second product [UO2Cl2(H2O)(3)](16).(15-crown-5)(16) 2 which displays an extremely complex hydrogen bonded chain structure in the solid state.

引用

页码：577 / 578

页数：2

共 24 条

[1]

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[2] CRYSTAL-STRUCTURES OF ACID HYDRATES AND OXONIUM SALTS .12. HYDRATED PROTON H+(H2O)N .6. NEUTRON-DIFFRACTION STUDY OF ISOLATED GROUP H5O2+.H2O IN ORTHO-SULFOBENZOIC ACID TRIHYDRATE [J].