Recent developments in lignin modification and its application in lignin-based green composites: A review

被引：86

作者：

Agustiany, Erika Ayu ^{[1
,2
]}

Rasyidur Ridho, Muhammad ^{[1
,2
]}

Rahmi D. N., Muslimatul ^{[1
,2
]}

Madyaratri, Elvara Windra ^{[1
,2
]}

Falah, Faizatul ^{[2
]}

Lubis, Muhammad Adly Rahandi ^{[2
]}

Solihat, Nissa Nurfajrin ^{[2
]}

Syamani, Firda A. ^{[2
,3
]}

Karungamye, Petro ^{[4
]}

Sohail, Asma ^{[5
]}

Nawawi, Deded Sarip ^{[1
]}

Prianto, Arief Heru ^{[2
]}

Iswanto, Apri Heri ^{[6
,7
]}

Ghozali, Muhammad ^{[8
]}

Restu, Witta Kartika ^{[8
]}

Juliana, Ika ^{[9
]}

Antov, Petar ^{[10
]}

Kristak, Lubos ^{[11
]}

Fatriasari, Widya ^{[2
,3
]}

Fudholi, Ahmad ^{[12
,13
]}

机构：

[1] IPB Univ, Fac Forestry & Environm, Dept Forest Prod, Bogor, Indonesia

[2] Natl Res & Innovat Agcy BRIN, Res Ctr Biomass & Bioprod, Bogor, Indonesia

[3] Res Collaborat Ctr Marine Biomat, Jatinangor, Sumedang, Indonesia

[4] Univ Dodoma, Dept Chem, Dodoma, Tanzania

[5] Lahore Coll Women Univ, Dept Chem, Lahore, Pakistan

[6] Univ Sumatera Utara, Dept Forest Prod, Fac Forestry, Medan 20155, Indonesia

[7] JATI Sumatran Forestry Anal Study Ctr, Medan, Indonesia

[8] Natl Res & Innovat Agcy BRIN, Kawasan PUSPIPTEK, Res Ctr Chem, Tangerang Selatan, Indonesia

[9] PT Greenei Alam Indonesia, Tangerang Selatan, Indonesia

[10] Univ Forestry, Fac Forest Ind, Res Ctr Energy Convers & Conservat, Sofia, Bulgaria

[11] Tech Univ Zvolen, Fac Wood Sci & Technol, Zvolen, Slovakia

[12] Univ Kebangsaan Malaysia, Solar Energy Res Inst, Bangi, Malaysia

[13] Natl Res & Innovat Agcy BRIN, Tangerang Selatan, Indonesia

来源：

POLYMER COMPOSITES | 2022年 / 43卷 / 08期

关键词：

biocomposite applications; biopolymers; lignin chemistry; lignin compatibility; lignin modification; MECHANICAL-PROPERTIES; ANTIOXIDANT ACTIVITY; CHEMICAL-PROPERTIES; THERMAL-STABILITY; RUBBER COMPOSITES; PERFORMANCE; ADHESIVES; NANOFIBRILS; EXTRACTION; ELASTOMERS;

D O I：

10.1002/pc.26824

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

Lignins are the most important aromatic renewable natural resource today, serving as a sustainable, environmentally acceptable alternative feedstock to fossil-derived chemicals and polymers in a vast scope of value-added applications. Lignin is a biopolymeric molecule that, together with cellulose, is a fundamental component of higher vascular plants structural cell walls. It can be extracted from by-products of the pulp and paper industries, agricultural waste and residues, and biorefinery products. Lignin properties may vary depending on source and extraction method with carbon and aromatic as the main compositions in lignin structure. These rich compositions make lignin more valuable, allowing for the creation of high-value-added green composites. However, the complex structure of lignin creates low reactivity to interact with crosslinker, and hence chemical modification is substantial to overcome this problem. This review aimed to present and discuss lignin structure, variation of lignin chemical properties regarding its source and extraction process, recent advances in chemical modification of lignin to enhance its reactivity, and potential applications of modified lignin for manufacturing value-added biocomposites with enhanced properties and lower environmental impact, such as food handling/packaging, seed coating, automotive devices, 3D printing, rubber industry, and wood adhesives.

引用

页码：4848 / 4865

页数：18

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