Channels formation through photodimerization of guest molecules within solid inclusion compounds

被引:13
作者
Lavy, Tali [1 ]
Kaftory, Menahem [1 ]
机构
[1] Technion Israel Inst Technol, Schulich Fac Chem, IL-32000 Haifa, Israel
关键词
D O I
10.1039/b615032b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photodimerizations of pyridone or methyl pyridone which serve as guest molecules in crystalline inclusion compounds are associated with a decrease in the volume of the guest molecules; at the end of this single crystal to single crystal transformation channels are formed through which water molecules diffuse.
引用
收藏
页码:123 / 127
页数:5
相关论文
共 32 条
[1]  
[Anonymous], 1988, TOP CURR CHEM
[2]   Guest transport in a nonporous organic solid via dynamic van der Waals cooperativity [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A ;
Schottel, BL .
SCIENCE, 2002, 298 (5595) :1000-1002
[3]   Controlling van der Waals contacts in complexes of fullerene C60 [J].
Atwood, JL ;
Barbour, LJ ;
Heaven, MW ;
Raston, CL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (28) :3254-3257
[4]   Polymorphism of pure p-tert-butylcalix[4]arene:: subtle thermally-induced modifications [J].
Atwood, JL ;
Barbour, LJ ;
Lloyd, GO ;
Thallapally, PK .
CHEMICAL COMMUNICATIONS, 2004, (08) :922-923
[5]   Storage of methane and freon by interstitial van der Waals confinement [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
SCIENCE, 2002, 296 (5577) :2367-2369
[6]   X-RAY-DIFFRACTION EVIDENCE FOR AROMATIC PI HYDROGEN-BONDING TO WATER [J].
ATWOOD, JL ;
HAMADA, F ;
ROBINSON, KD ;
ORR, GW ;
VINCENT, RL .
NATURE, 1991, 349 (6311) :683-684
[7]   SINGLE-CRYSTAL-TO-SINGLE-CRYSTAL PHOTODIMERIZATION OF CINNAMIC ACID [J].
ENKELMANN, V ;
WEGNER, G ;
NOVAK, K ;
WAGENER, KB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) :10390-10391
[8]   TOPOCHEMICAL SOLID-STATE PHOTODIMERIZATION OF NON-IDEALLY ORIENTED MONOMERS - 7-CHLOROCOUMARIN AND 7-METHOXYCOUMARIN [J].
GNANAGURU, K ;
RAMASUBBU, N ;
VENKATESAN, K ;
RAMAMURTHY, V .
JOURNAL OF PHOTOCHEMISTRY, 1984, 27 (03) :355-362
[9]   The first in situ observation of intramolecular rotation and cyclization of anilide by an X-ray study:: Partial single-crystal to single-crystal photocyclization of N-methyl-N-{(E)-methylmethacryloyl}anilide in inclusion crystals [J].
Hosomi, H ;
Ohba, S ;
Tanaka, K ;
Toda, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (08) :1818-1819