Pt-Catalyzed Tandem 1,2-Acyloxy Migration/Intramolecular [3+2] Cycloaddition of Enynyl Esters

被引：60

作者：

Zheng, Huaiji ^{[1
]}

Zheng, Jiyue ^{[1
]}

Yu, Binxun ^{[1
]}

Chen, Qiang ^{[1
]}

Wang, Xiaolei ^{[1
]}

He, Yongping ^{[1
]}

Yang, Zhen ^{[1
]}

She, Xuegong ^{[1
]}

机构：

[1] Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 06期

关键词：

PROPARGYLIC ESTERS; GOLD; CYCLOISOMERIZATION; REARRANGEMENTS; PLATINUM; CYCLIZATION; N-ENYNES; ACTIVATION;

D O I：

10.1021/ja910346m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A platinum-catalyzed tandem reaction involving enynyl ester isomerization and subsequent intramolecular [3 + 2] cyclization has been developed. This strategy provides an efficient approach to five-, six-, or seven-membered cyclic polyfunctional compounds.

引用

页码：1788 / +

页数：3

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