The structure of Y-Al13-xCo4 (x=0.8) analyzed by single crystal X-ray diffraction coupled with anomalous X-ray scattering

被引：9
作者：
Sugiyama, Kazumasa [1 ]
Genba, Michiyo [2 ]
Hiraga, Kenji [1 ]
Waseda, Yoshio [3 ]
机构：
[1] Tohoku Univ, Inst Mat Res, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Univ Tokyo, Grad Sch Sci, Dept Earth & Planetary Sci, Bunkyo Ku, Tokyo 1130033, Japan
[3] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 494卷 / 1-2期
基金：
日本学术振兴会;
关键词：
Y-phase; Al-Co system; Crystal structure; Anomalous; X-ray scattering; Approximant; DECAGONAL QUASI-CRYSTAL; APPROXIMANT; CO4AL13;
D O I：
10.1016/j.jallcom.2009.11.117
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The structure of Y-Al13-xCo4 (x=0.8) has been analyzed by single crystal X-ray diffraction: space group C2/m (No.12), a=17.0525 (20)angstrom, 6=4.1059(6)angstrom, c=7.5047(9)angstrom, beta=116.01(1)degrees. Y- Al13-0.8Co4 is isostructural with a ternary Y-A113-x(Co,Ni)4 and crystallized at the Al-poor region close to Al(13)Co4. The distribution of Co was also confirmed by anomalous X-ray scattering (AXS) at Co K absorption edge. Present analysis revealed the Co distribution at Co(1) and Co(2) sites, only, by suggesting unique pentagonal atomic columns with a period of 4 angstrom different from that observed in Al11Co4. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：98 / 101
页数：4
相关论文
共 50 条
  • [41] Compressibility of hingganite-(Y): high-pressure single crystal X-ray diffraction study
    Liudmila A. Gorelova
    Anna S. Pakhomova
    Sergey V. Krivovichev
    Anatoly V. Kasatkin
    Leonid S. Dubrovinsky
    Physics and Chemistry of Minerals, 2020, 47
  • [42] X-ray resonant powder diffraction
    Palancher, H.
    Bos, S.
    Berar, J. F.
    Margiolaki, I.
    Hodeau, J. L.
    EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS, 2012, 208 (01) : 275 - 289
  • [43] X-ray single crystal refinement of the Ho3Si4 structure
    Ijjaali, I
    Venturini, G
    Malaman, B
    JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 269 (1-2) : L6 - L8
  • [44] Single crystal X-ray structure investigation of Cu2ZnSnSe4
    Nateprov A.
    Kravtsov V.C.
    Gurieva G.
    Schorr S.
    Surface Engineering and Applied Electrochemistry, 2013, 49 (05) : 423 - 426
  • [45] X-ray single crystal structure and raman spectrum of ammonium hexafluoroarsenate
    Goreshnik, E.
    Mazej, Z.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (08): : 1271 - 1273
  • [46] THE SINGLE-CRYSTAL X-RAY STRUCTURE OF GAGARINITE-(Ce)
    Sciberras, Matthew J.
    Leverett, Peter
    Williams, Peter A.
    Hibbs, David E.
    Roberts, Andrew C.
    Grice, Joel D.
    CANADIAN MINERALOGIST, 2011, 49 (04) : 1111 - 1114
  • [47] Detectors for X-ray diffraction and scattering:: a user's overview
    Brügemann, L
    Gerndt, EKE
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2004, 531 (1-2) : 292 - 301
  • [48] Source, optical and detector requirements for X-ray diffraction and scattering
    Nave, C
    JOURNAL OF SYNCHROTRON RADIATION, 1998, 5 : 645 - 647
  • [49] Crystal structure of CuFe2InSe4 from X-ray powder diffraction
    Delgado, G. E.
    Mora, A. J.
    Grima-Gallardo, R.
    Quintero, M.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 454 (1-2) : 306 - 309
  • [50] Crystal structure and morphology of disordered AlNbO4 from X-ray powder diffraction
    Greis, O
    Ziel, R
    Garcia, DE
    Claussen, N
    Breidenstein, B
    Haase, A
    EUROPEAN POWDER DIFFRACTION: EPDIC IV, PTS 1 AND 2, 1996, 228 : 825 - 830
12345