{[Mn2(μ3-Tda)2(μ-H2O)(H2O)2(bipy)]•DMF}n -: a 2D Manganese(II) coordination polymer involving six-membered binuclear metallacycle nodes

被引：3
作者：
Cheng, Ya-Qian
Xiao, Hong-Ping
Li, Xin-Hua
Wang, Jia-Guo
Morsali, Ali
机构：
[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran
[2] Wenzhou Univ, Sch Chem & Mat Sci, Wenzhou, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 08期
关键词：
manganese; coordination polymers; thiophene-2,5-dicarboxylic acid; 2,2 '-bipyridine;
D O I：
10.1002/zaac.200700117
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The single crystal X-ray analysis of a novel thiophene2,5-dicarboxylic acid (H(2)Tda) Manganese(II) coordination polyrner, Mn-2(mu(3)-Tda)(2)( mu-H2O)(H2O)(2)(bipy)] center dot DMF}(n), shows two different types of Mn2+:-ions with environment of MnIO6 and Mn2O(4)N(2), and the complex is a two-dimensional polymer as a result of bridging (Tda)(2-) ligands and by connecting the carboxylate- and water-bridged {Mn-2(mu-Tda)(2)(mu-H2O) nodes.
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收藏
页码：1140 / 1142
页数：3
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