Preparation of TiC/W core-shell structured powders by one-step activation and chemical reduction process

被引:21
作者
Ding, Xiao-Yu [1 ]
Luo, Lai-Ma [1 ,3 ]
Huang, Li-Mei [1 ]
Luo, Guang-Nan [2 ]
Zhu, Xiao-Yong [1 ,3 ]
Cheng, Ji-Gui [1 ,3 ]
Wu, Yu-Cheng [1 ,3 ]
机构
[1] Hefei Univ Technol, Coll Mat Sci & Engn, Hefei 230009, Peoples R China
[2] Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Peoples R China
[3] Engn Res Ctr Powder Met Anhui Prov, Hefei 230009, Peoples R China
基金
中国国家自然科学基金;
关键词
One-step activation; Chemical reduction; TiC/W; Core-shell; COMPOSITES; TUNGSTEN; NANOPARTICLES; ENHANCEMENT; EVOLUTION; STRENGTH; ALLOYS;
D O I
10.1016/j.jallcom.2014.08.242
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present study, one-step activation and chemical reduction process as a novel wet-chemical route was performed for the preparation of TiC/W core-shell structured ultra-fine powders. The XRD, FE-SEM, TEM and EDS results demonstrated that the as-synthesized powders are of high purity and uniform with a diameter of approximately 500 nm. It is also found that the TiC nanoparticles were well-encapsulated by W shells. Such a unique process suggests a new method for preparing X/W (X refers the water-insoluble nanoparticles) core-shell nanoparticles with different cores. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:704 / 708
页数:5
相关论文
共 24 条
[1]   Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications [J].
Chaudhuri, Rajib Ghosh ;
Paria, Santanu .
CHEMICAL REVIEWS, 2012, 112 (04) :2373-2433
[2]   Morphological evolution of second-phase particles during thermomechanical processing of W-La2O3 alloy [J].
Chen, ZC ;
Zhou, ML ;
Zuo, TY .
SCRIPTA MATERIALIA, 2000, 43 (04) :291-297
[3]   Microstructural characterizations of Ni activated sintered W-2 wt% TiC composites produced via mechanical alloying [J].
Genc, A. ;
Coskun, S. ;
Ovecoglu, M. L. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 497 (1-2) :80-89
[4]   Decarburization of TiC in Ni activated sintered W-xTiC (x=0, 5, 10, 15 wt%) composites and the effects of heat treatment on the microstructural and physical properties [J].
Genc, A. ;
Coskun, S. ;
Ovecoglu, M. L. .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2010, 28 (03) :451-458
[5]   Effects of plastic working and MA atmosphere on microstructures of recrystallized W-1.1%TiC [J].
Kajioka, Michio ;
Sakamoto, Tatsuaki ;
Nakai, Kiyomichi ;
Kobayashi, Sengo ;
Kurishita, Hiroaki ;
Matsuo, Satoru ;
Arakawa, Hideo .
JOURNAL OF NUCLEAR MATERIALS, 2011, 417 (1-3) :512-515
[6]   Development of ultra-fine grained W-(0.25-0.8)wt%TiC and its superior resistance to neutron and 3 MeV He-ion irradiations [J].
Kurishita, H. ;
Kobayashi, S. ;
Nakai, K. ;
Ogawa, T. ;
Hasegawa, A. ;
Abe, K. ;
Arakawa, H. ;
Matsuo, S. ;
Takida, T. ;
Takebe, K. ;
Kawai, M. ;
Yoshida, N. .
JOURNAL OF NUCLEAR MATERIALS, 2008, 377 (01) :34-40
[7]   Superplastic deformation in W-0.5 wt.% TiC with approximately 0.1 μm grain size [J].
Kurishita, H. ;
Matsuo, S. ;
Arakawa, H. ;
Kobayashi, S. ;
Nakai, K. ;
Takida, T. ;
Takebe, K. ;
Kawai, M. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 477 (1-2) :162-167
[8]   Development of ultra-fine grained W-TiC and their mechanical properties for fusion applications [J].
Kurishita, H. ;
Amano, Y. ;
Kobayashi, S. ;
Nakai, K. ;
Arakawa, H. ;
Hiraoka, Y. ;
Takida, T. ;
Takebe, K. ;
Matsui, H. .
JOURNAL OF NUCLEAR MATERIALS, 2007, 367 :1453-1457
[9]   Development of re-crystallized W-1.1%TiC with enhanced room-temperature ductility and radiation performance [J].
Kurishita, H. ;
Matsuo, S. ;
Arakawa, H. ;
Sakamoto, T. ;
Kobayashi, S. ;
Nakai, K. ;
Takida, T. ;
Kato, M. ;
Kawai, M. ;
Yoshida, N. .
JOURNAL OF NUCLEAR MATERIALS, 2010, 398 (1-3) :87-92
[10]   High temperature tensile properties and their application to toughness enhancement in ultra-fine grained W-(0-1.5)wt% TiC [J].
Kurishita, H. ;
Matsuo, S. ;
Arakawa, H. ;
Narui, M. ;
Yamazaki, M. ;
Sakamoto, T. ;
Kobayashi, S. ;
Nakai, K. ;
Takida, T. ;
Takebe, K. ;
Kawai, M. ;
Yoshida, N. .
JOURNAL OF NUCLEAR MATERIALS, 2009, 386-88 :579-582