Highly Efficient Flexible Perovskite Solar Cells Using Solution-Derived NiOx Hole Contacts

被引:432
作者
Yin, Xingtian [1 ]
Chen, Peng [1 ]
Que, Meidan [1 ]
Xing, Yonglei [1 ]
Que, Wenxiu [1 ]
Niu, Chunming [2 ]
Shao, Jinyou [3 ]
机构
[1] Xi An Jiao Tong Univ, Elect Mat Res Lab, Int Ctr Dielect Res, Key Lab,Minist Educ,Sch Elect & Informat Engn, Xian 710049, Shaanxi, Peoples R China
[2] Xi An Jiao Tong Univ, CNRE, State Key Lab Elect Insulat & Power Equipment, Sch Elect Engn, Xian 710049, Shaanxi, Peoples R China
[3] Xi An Jiao Tong Univ, State Key Lab Mfg Syst Engn, Xian 710049, Shaanxi, Peoples R China
基金
高等学校博士学科点专项科研基金; 中国国家自然科学基金; 中国博士后科学基金;
关键词
NiOx; hole contact; flexible; perovskite solar cell; HIGH-PERFORMANCE; SEQUENTIAL DEPOSITION; LOW-TEMPERATURE; HYSTERESIS; CH3NH3PBI3; LAYERS; FILM;
D O I
10.1021/acsnano.5b08135
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A solution-derived NiOx film was employed as the hole contact of a flexible organic inorganic hybrid perovskite solar cell. The NiOx film, which was spin coated from presynthesized NiOx nanoparticles solution, can extract holes and block electrons efficiently, without any other post-treatments. An optimal power conversion efficiency (PCE) of 16.47% was demonstrated in the NiOx-based perovskite solar cell on an ITO-glass substrate, which is much higher than that of the perovskite solar cells using high temperature-derived NiOx film contacts. The low -temperature deposition process made the NiOx films suitable for flexible devices. NiOx-based flexible perovskite solar cells were fabricated on ITO-PEN substrates, and a preliminary PCE of 13.43% was achieved.
引用
收藏
页码:3630 / 3636
页数:7
相关论文
共 37 条
[1]   The Swift Surge of Perovskite Photovoltaics [J].
Bisquert, Juan .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (15) :2597-2598
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide [J].
Christians, Jeffrey A. ;
Fung, Raymond C. M. ;
Kamat, Prashant V. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :758-764
[4]   CH3NH3PbI3-Based Planar Solar Cells with Magnetron-Sputtered Nickel Oxide [J].
Cui, Jin ;
Meng, Fanping ;
Zhang, Hua ;
Cao, Kun ;
Yuan, Huailiang ;
Cheng, Yibing ;
Huang, Feng ;
Wang, Mingkui .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (24) :22862-22870
[5]   Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates [J].
Docampo, Pablo ;
Ball, James M. ;
Darwich, Mariam ;
Eperon, Giles E. ;
Snaith, Henry J. .
NATURE COMMUNICATIONS, 2013, 4
[6]   Hysteresis-less inverted CH3NH3PbI3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency [J].
Heo, Jin Hyuck ;
Han, Hye Ji ;
Kim, Dasom ;
Ahn, Tae Kyu ;
Im, Sang Hyuk .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (05) :1602-1608
[7]   PbS colloidal quantum dots as an effective hole transporter for planar heterojunction perovskite solar cells [J].
Hu, Long ;
Wang, Weiwei ;
Liu, Huan ;
Peng, Jun ;
Cao, Hefeng ;
Shao, Gang ;
Xia, Zhe ;
Ma, Wanli ;
Tang, Jiang .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (02) :515-518
[8]   Sequential Deposition of CH3NH3PbI3 on Planar NiO Film for Efficient Planar Perovskite Solar Cells [J].
Hu, Long ;
Peng, Jun ;
Wang, Weiwei ;
Xia, Zhe ;
Yuan, Jianyu ;
Lu, Jialing ;
Huang, Xiaodong ;
Ma, Wanli ;
Song, Huaibing ;
Chen, Wei ;
Cheng, Yi-Bing ;
Tang, Jiang .
ACS PHOTONICS, 2014, 1 (07) :547-553
[9]   6.5% efficient perovskite quantum-dot-sensitized solar cell [J].
Im, Jeong-Hyeok ;
Lee, Chang-Ryul ;
Lee, Jin-Wook ;
Park, Sang-Won ;
Park, Nam-Gyu .
NANOSCALE, 2011, 3 (10) :4088-4093
[10]   A Solution-Processed MoOx Anode Interlayer for Use within Organic Photovoltaic Devices [J].
Jasieniak, Jacek J. ;
Seifter, Jason ;
Jo, Jang ;
Mates, Tom ;
Heeger, Alan J. .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (12) :2594-2605