Novel 3D Nitrogen-Rich Metal Organic Framework for Highly Efficient CO2 Adsorption and Catalytic Conversion to Cyclic Carbonates under Ambient Temperature

被引：124
作者：
Lan, Jianwen [1 ]
Liu, Mengshuai [2 ]
Lu, Xingyuan [3 ]
Zhang, Xiao [1 ]
Sun, Jianmin [1 ,4 ]
机构：
[1] Harbin Inst Technol, Sch Chem & Chem Engn, State Key Lab Urban Water Resource & Environm, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150080, Heilongjiang, Peoples R China
[2] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
[3] Northeast Forestry Univ, Sch Sci, Harbin 150040, Heilongjiang, Peoples R China
[4] Harbin Inst Technol Shenzhen, Shenzhen Key Lab Organ Pollut Prevent & Control, Shenzhen 518055, Peoples R China
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 07期
基金：
中国国家自然科学基金;
关键词：
carbon dioxide; cyclic carbonate; Lewis acid base; Zn-based MOF; heterogeneous catalysis; DENSITY-FUNCTIONAL THEORY; CHEMICAL FIXATION; IONIC LIQUIDS; EPOXIDES; DIOXIDE; CAPTURE; CYCLOADDITION; POLYMERS; WATER;
D O I：
10.1021/acssuschemeng.8b01055
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel Lewis acid base bifunctional Zn(II)-based MOF-Zn-1 [Zn(2)L(2)MA center dot 2DMF] (MA = melamine, H2L = 2,5-thiophenedicarboxylic acid), with abundant micropores and free-NH2 groups was facilely assembled by incorporating zinc(II) ion with nitrogen-rich melamine and 2,5-thiophenedicarboxylic acid ligands. The constructed MOF-Zn-1 presented an excellent affinity toward CO2 molecules due to the Lewis-base property together with abundant micropores. The Zn active sites could be used for epoxide activation. The acid-base synergistic effects facilitated CO2 conversion into cyclic carbonates under ambient temperature using the porous MOF-Zn-1 as a heterogeneous catalyst. Moreover, the MOF-Zn-1 exhibited satisfied stability and versatility, and it was easy to recycle with no obvious decrease of catalytic activity. Then the feasible synergistic mechanism of MOF-Zn-1/Bu4NBr catalysts for CO2 conversion was proposed.
引用
收藏
页码：8727 / 8735
页数：17
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