An Aza-Diels-Alder Route to Polyquinolines

被引：33

作者：

Dibble, David J. ^{[1
]}

Umerani, Mehran J. ^{[1
]}

Mazaheripour, Amir ^{[1
]}

Park, Young S. ^{[1
]}

Ziller, Joseph W. ^{[2
]}

Gorodetsky, Alon A. ^{[1
,2
]}

机构：

[1] Univ Calif Irvine, Dept Chem Engn & Mat Sci, Irvine, CA 92697 USA

[2] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

MACROMOLECULES | 2015年 / 48卷 / 03期

关键词：

ELECTRON-TRANSPORT MATERIALS; BIOLOGICAL-ACTIVITIES; CONJUGATED POLYMERS; AROMATIC POLYQUINOLINES; QUINOLINE; ELECTROLUMINESCENCE; COPOLYMERS; SPECTRA; DERIVATIVES; FACILE;

D O I：

10.1021/ma5020726

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyquinolines have been studied since the early 1970s due to their favorable chemical, optical, electrical, and mechanical properties. However, surprisingly few synthetic strategies have been developed for the preparation of these polymers. Herein, we demonstrate the application of the aza-DielsAlder (Povarov) reaction for the synthesis of soluble polyquinolines from a bifunctional monomer. Our approach furnishes polyquinolines with a unique architecture and connectivity in only two synthetic steps from inexpensive, commercially available reagents. The reported strategy may therefore represent a welcome addition to the polymer chemists toolkit by providing ready access to a diverse library of polyquinoline-type materials.

引用

页码：557 / 561

页数：5

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