A comparative UV-vis-diffuse reflectance study on the location and interaction of cerium ions in Al- and Zr-pillared montmorillonite clays

被引:47
作者
Rao, GR [1 ]
Mishra, BG [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
关键词
pillared clay; UV-vis-DRS; cerium ion; XRD; montmorillonite;
D O I
10.1016/j.matchemphys.2004.08.037
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The environment, location and interaction of the Ce3+ ions in the micropores of Al- and Zr-pillared clays have been studied by UV-vis-diffuse reflectance spectroscopy (UV-vis-DRS). The DRS spectra show that the chemical environment of the Ce3+ ions in cerium exchanged clay is different from that of the Al- and Zr-pillared clays. The Al-Ce pillared clays (Al-Ce-PM) show four distinct absorption bands at 224, 263, 294 and 342 nm in the UV region which are attributed to 4f --> 5d interconfigurational transitions of Ce3+ ions associated with alumina pillars. The O-2 --> C3+ charge transfer band observed at 263 nm for Ce-exchanged and Al-Ce-PM clays is blue shifted by 10 nm for Ce-Zr-pillared clays (Ce-Zr-PM) due to fully hydrated Ce3+ ions. The Ce3+ ions are incorporated in the Al- and Zr-pillars possibly as AlCeO3 and CexZr1-xO2 particles upon heat treatment. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:110 / 115
页数:6
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