Bimetallic catalytic cascade ring closing metathesis - intramolecular Heck reactions using a fluorous biphasic solvent system or a polymer-supported palladium catalyst

被引：61
作者：
Grigg, R [1 ]
York, M [1 ]
机构：
[1] Univ Leeds, Sch Chem, MIDAS, Leeds LS2 9JT, W Yorkshire, England
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 37期
基金：
英国工程与自然科学研究理事会;
关键词：
metathesis; Grubbs catalyst; Heck; palladium catalysis; fluorous biphasic; polymer support; cascade reaction; bimetallic;
D O I：
10.1016/S0040-4039(00)01250-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The combination of ring closing metathesis and intramolecular Heck reactions in a cascade gives bridged ring systems in good yield. Two methods using either a fluorous biphasic solvent system or a polymer-supported palladium catalyst overcome the observed incompatibility of the catalysts. (C) 2000 Elsevier Science Ltd, All rights reserved.
引用
收藏
页码：7255 / 7258
页数：4
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