Tandem N-alkylation-C-allylation reaction of α-imino esters with organoaluminums and allyltributyltin

被引：87

作者：

Niwa, Y ^{[1
]}

Shimizu, M ^{[1
]}

机构：

[1] Mie Univ, Dept Chem Mat, Tsu, Mie 5148507, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 13期

关键词：

D O I：

10.1021/ja029639o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On treatment of various α-imino esters with organoaluminum reagents and allyltributyltin in the presence of benzoyl peroxide, the tandem reaction proceeded to give the N-alkylation-C-allylation products in good yields. The tandem N-alkyation-C-cyanation also proceeded using silyl or aluminum cyanide to give the aminonitrile in good yield. Copyright © 2003 American Chemical Society.

引用

页码：3720 / 3721

页数：2

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