Mechanical and electrical properties of high performance MWCNT/polycarbonate composites prepared by an industrial viable twin screw extruder with back flow channel

被引:50
作者
Babal, Arun Singh [1 ]
Gupta, Ravi [1 ]
Singh, Bhanu Pratap [1 ]
Singh, Vidya Nand [2 ]
Dhakate, Sanjay R. [1 ]
Mathur, Rakesh B. [1 ]
机构
[1] CSIR, Natl Phys Lab, New Delhi 110012, India
[2] CSIR, Natl Phys Lab, Electron & Ion Microscopy Sect, New Delhi 110012, India
关键词
MULTIWALLED CARBON NANOTUBES; SHIELDING EFFECTIVENESS; SINGLE-WALL; POLYCARBONATE; CONDUCTIVITY; MORPHOLOGY; DISPERSION; BEHAVIOR;
D O I
10.1039/c4ra11319e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High performance multiwall carbon nanotube (MWCNT) reinforced polycarbonate (PC) composites were prepared using an industrially viable fast dispersion process by a micro twin screw extruder with back flow channel and their mechanical and electrical properties were investigated for EMI shielding applications. A uniformly dispersed MWCNT/PC composite system was observed through SEM and TEM investigations. Incorporation of a small amount of MWCNT (2 wt%) led to enhancements in the tensile strength (up to 79.6 MPa) and flexural strength (up to 110 MPa), which were equivalent to 19.6% and 14.6% increases over the neat PC. The effect of MWCNTs on the failure mechanism of the PC under tensile loading showed a ductile to brittle transition with increasing concentration of MWCNTs. The results of enhanced mechanical properties were well supported by micro Raman spectroscopic studies. In addition to the mechanical properties, significant improvement in the electrical conductivity (0.01 S cm(-1) at 10 wt% MWCNT) of these composites was observed which yielded the EMI shielding of -27.2 dB in the Ku band suggesting their possible use as a high strength EMI shielding material.
引用
收藏
页码:64649 / 64658
页数:10
相关论文
共 46 条
[1]   Rheological characterization of melt processed polycarbonate-multiwalled carbon nanotube composites [J].
Abdel-Goad, M ;
Pötschke, P .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 2005, 128 (01) :2-6
[2]  
[Anonymous], 2003, Introduction To Percolation Theory
[3]   Electrical and electromagnetic interference shielding properties of flow-induced oriented carbon nanotubes in polycarbonate [J].
Arjmand, Mohammad ;
Mahmoodi, Mehdi ;
Gelves, Genaro A. ;
Park, Simon ;
Sundararaj, Uttandaraman .
CARBON, 2011, 49 (11) :3430-3440
[4]   DC and AC conductivity of carbon nanotubes-polyepoxy composites [J].
Barrau, S ;
Demont, P ;
Peigney, A ;
Laurent, C ;
Lacabanne, C .
MACROMOLECULES, 2003, 36 (14) :5187-5194
[5]   Raman spectroscopic characterization of multiwall carbon nanotubes and of composites [J].
Bokobza, L. ;
Zhang, J. .
EXPRESS POLYMER LETTERS, 2012, 6 (07) :601-608
[6]   Study on polycarbonate/multi-walled carbon nanotubes composite produced by melt processing [J].
Chen, Li ;
Pang, Xiu-Jiang ;
Yu, Zuo-Long .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 457 (1-2) :287-291
[7]   Electromagnetic interference shielding effectiveness of carbon materials [J].
Chung, DDL .
CARBON, 2001, 39 (02) :279-285
[8]  
Dresselhaus M. S., 1996, SCI FULLERENES CARBO
[9]   Reinforcement mechanisms in MWCNT-filled polycarbonate [J].
Eitan, A. ;
Fisher, F. T. ;
Andrews, R. ;
Brinson, L. C. ;
Schadler, L. S. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2006, 66 (09) :1162-1173
[10]   Morphology and properties of melt-spun polycarbonate fibers containing single- and multi-wall carbon nanotubes [J].
Fornes, TD ;
Baur, JW ;
Sabba, Y ;
Thomas, EL .
POLYMER, 2006, 47 (05) :1704-1714