Thermal crosslinking of silicone pressure-sensitive adhesives using organic peroxides

被引:19
作者
Antosik, Adrian Krzysztof [1 ]
Raganska, Paulina [1 ]
Czech, Zbigniew [1 ]
机构
[1] Zachodniopomorski Uniwersytet Technol Szczecinie, Inst Technol Chem Organicznej, PL-70322 Szczecin, Poland
关键词
silicone pressure-sensitive adhesives (Si-PSA); peel adhesion; cohesion; tack; thermal crosslinking; benzoyl peroxide; dichlorobenzoyl peroxide; DELIVERY; TAPES;
D O I
10.14314/polimery.2014.792
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of the concentration of crosslinking agent [benzoyl peroxide (BPO) and dichlorobenzoyl peroxide (DClBPO), in the range of 0.5 - 3.0 wt. %] on the crosslinking process of the selected silicone pressure-sensitive adhesives (Si-PSA) was investigated. All of the tested silicone adhesives showed excellent peel adhesion and high cohesion. In most cases, an increase in the crosslinking agent concentration resulted in the improved cohesion and reduced peel adhesion of Si-PSA. The specific parameters of the investigated silicone pressure-sensitive adhesives such as cohesion and peel adhesion can be obtained by a suitable selection of organic peroxide additive.
引用
收藏
页码:792 / 797
页数:6
相关论文
共 20 条
[1]  
[Anonymous], 2013, Pat. USA, Patent No. [2013/0150535, 20130150535]
[2]  
[Anonymous], 1992, Pat. USA, Patent No. [5 162 410, 5162410]
[3]  
[Anonymous], 1993, Pat. USA, Patent No. [5 248 739, 5248739]
[4]   Crosslinking of pressure sensitive adhesive based on water-borne acrylate [J].
Czech, Z .
POLYMER INTERNATIONAL, 2003, 52 (03) :347-357
[5]   Solvent-based pressure-sensitive adhesives for removable products [J].
Czech, Z .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2006, 26 (06) :414-418
[6]  
Czech Z, 2008, CZAS TECH CHEM, V2, P293
[7]  
Czech Z., 2009, WIAD CHEM, V63, P269
[8]  
Czech Z., 2009, EUR POLYM J, V29, P186
[9]   Biodegradable self-adhesive tapes with starch carrier [J].
Czech, Zbigniew ;
Wilpiszewska, Katarzyna ;
Tyliszczak, Bozena ;
Jiang, Xu ;
Bai, Yongping ;
Shao, Lu .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2013, 44 :195-199
[10]   The influence of the polymerization on properties of an ethylacrylate/2-ethyl hexylacrylate pressure-sensitive adhesive suspension [J].
Kajtna, J. ;
Likozar, B. ;
Golob, J. ;
Krajnc, M. .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2008, 28 (07) :382-390