Is there a need for new models of the spin crossover?

被引：69

作者：

Boca, R ^{[1
]}

Linert, W

机构：

[1] Slovak Univ Technol Bratislava, Dept Inorgan Chem, SK-81237 Bratislava, Slovakia

[2] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria

来源：

MONATSHEFTE FUR CHEMIE | 2003年 / 134卷 / 02期

关键词：

spin crossover; domain model; solution model; statistical model; cooperativeness;

D O I：

10.1007/s00706-002-0489-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The existing models of the low-spin to high-spin transition (spin crossover) are briefly reviewed. Experimental data pointing to a need of new models are displayed. A statistical model with the distribution of the solid-state cooperativeness is outlined. A modeling is shown as well as its application to a spin crossover system [Fe(bzimpy)(2)](ClO4)(2) (.) 0.25H(2)O. This shows an abrupt spin crossover at temperature as high as 403 K with a hysteresis width of 12 K. The angled walls of the hysteresis loop can be followed by the outlined statistical model.

引用

页码：199 / 216

页数：18

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