Isolation of a Small Carbon Nanotube: The Surprising Appearance of D5h(1)-C90

被引:74
|
作者
Yang, Hua [1 ]
Beavers, Christine M. [3 ]
Wang, Zhimin [1 ]
Jiang, An [1 ]
Liu, Ziyang [1 ]
Jin, Hongxiao [4 ]
Mercado, Brandon Q. [2 ]
Olmstead, Marilyn M. [2 ]
Balch, Alan L. [2 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA
[4] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Peoples R China
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
carbon nanotubes; fullerenes; samarium; X-ray diffraction; CRYSTALLOGRAPHIC CHARACTERIZATION; STRUCTURE ELUCIDATION; ELECTRONIC-STRUCTURE; STABLE ISOMERS; FULLERENES; C-60; TEMPERATURE;
D O I
10.1002/anie.200906023
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Totally tubular: The previously undetected higher fullerene D 5h(1)-C90 (see structure) was isolated as the major C 90 isomer produced from Sm2O3-doped graphite rods and identified structurally by X-ray crystallography. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:886 / 890
页数:5
相关论文
共 28 条
  • [1] Theoretical study on the interaction of oxygen atom with C90 (D5h)
    Wang, Donglai
    Wang, Xin
    Gao, Xu
    Hou, Dongyan
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2012, 989 : 33 - 38
  • [2] Semiconducting and Metallic [5,5] Fullertube Nanowires: Characterization of Pristine D5h(1)-C90 and D5d(1)-C100
    Stevenson, Steven
    Liu, Xiaoyang
    Sublett, D. Mathew, Jr.
    Koenig, Ryan M.
    Seeler, Tiffany L.
    Tepper, Katelyn R.
    Franklin, Hannah M.
    Wang, Xiaoling
    Huang, Rong
    Feng, Xu
    Cover, Kevin
    Troya, Diego
    Shanaiah, Narasimhamurthy
    Bodnar, Robert J.
    Dorn, Harry C.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (12) : 4593 - 4599
  • [3] Ordered Structures from Crystalline Carbon Disulfide Solvates of the Nano-Tubular Fullerenes D5h(1)-C90 and D5h-C70
    Bowles, Faye L.
    Mercado, Brandon Q.
    Ghiassi, Kamran B.
    Chen, Susanne Y.
    Olmstead, Marilyn M.
    Yang, Hua
    Liu, Ziyang
    Balch, Alan L.
    CRYSTAL GROWTH & DESIGN, 2013, 13 (10) : 4591 - 4598
  • [4] Nanotube-Like Electronic States in [5,5]-C90 Fullertube Molecules
    Jover, Oscar
    Martin-Jimenez, Alberto
    Franklin, Hannah M.
    Koenig, Ryan M.
    Martinez, Jose I.
    Martin, Nazario
    Lauwaet, Koen
    Miranda, Rodolfo
    Gallego, Jose M.
    Stevenson, Steven
    Otero, Roberto
    SMALL, 2024, 20 (09)
  • [5] Theoretical Studies on Molecular Behavior of C50 ( D5h ) Derivative: Heterofullerene C48P2
    Xu Xiu-Fang
    Shang Zhen-Feng
    Li Rui-Fang
    Zhao Xue-Zhuang
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2009, 30 (06): : 1219 - 1226
  • [6] Quantum Chemical Insight of the Dimetallic Sulfide Endohedral Fullerene Sc2S@C70: Does It Possess the Conventional D5h Cage?
    Yang, Tao
    Zhao, Xiang
    Nagase, Shigeru
    CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (08) : 2649 - 2654
  • [7] Photoreactions of Sc3N@C80 with Disilirane, Silirane, and Digermirane: A Photochemical Method to Separate Ih and D5h Isomers
    Kako, Masahiro
    Miyabe, Kyosuke
    Fukazawa, Shinpei
    Kanzawa, Shinji
    Yasui, Masanori
    Yamada, Michio
    Maeda, Yutaka
    Slanina, Zdenek
    Uhlik, Filip
    Adamowicz, Ludwik
    Papadopoulos, Ilias
    Guldi, Dirk M.
    Furukawa, Makoto
    Nagase, Shigeru
    Akasaka, Takeshi
    PHOTOCHEM, 2022, 2 (01): : 122 - 137
  • [8] Synthesis and Characterization of the D5h Isomer of the Endohedral Dimetallofullerene Ce2@C80: Two-Dimensional Circulation of Encapsulated Metal Atoms Inside a Fullerene Cage
    Yamada, Michio
    Mizorogi, Naomi
    Tsuchiya, Takahiro
    Akasaka, Takeshi
    Nagase, Shigeru
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (37) : 9486 - 9493
  • [9] An Open-Cage Fullerene That Mimics the C60H10 (5,5)-Carbon Nanotube Endcap to Host Acetylene and Hydrogen Cyanide Molecules
    Chen, Chi-Shian
    Yeh, Wen-Yann
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (46) : 16425 - 16428
  • [10] Silicon doping on nanotubular fullerene D5h-C90 from first principles
    Bai, Hongcun
    Xue, Ping
    Tao, Jia-Yuan
    Ji, Wen-Xin
    Han, Zhi-Min
    Ma, Yujia
    Ji, Yongqiang
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2015, 1069 : 138 - 146