C-H bond activation by rhodium(I) hydroxide and phenoxide complexes

被引：98

作者：

Kloek, Susan M. ^{[1
]}

Heinekey, D. Michael ^{[1
]}

Goldberg, Karen L. ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 25期

关键词：

C-H activation; H/D exchange; hydroxide ligands; NMR spectroscopy; rhodium;

D O I：

10.1002/anie.200700270

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rhodium(I) complexes of the form [(PNP)Rh(OR)] (R = H, CH2CF3, C6H5; PNP = 2,6-bis[(di-tert-butylphosphino)methyl]pyridine) have been prepared. Upon thermolysis in [D6]benzene, the hydroxide and trifluoroethoxide complexes undergo benzene activation. [(PNP)Rh(OC6H5)] is an active catalyst for the H/D exchange between D2O and benzene and between H2O and [D8]toluene (see scheme), for which exchange occurs selectively at the meta and para positions. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4736 / 4738

页数：3

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