A chlorophobic pocket in the p-tert-butylcalix[4]arene cavity:: A test site for molecular recognition investigated by 13C CP MAS NMR and X-ray crystallography

被引：35

作者：

Brouwer, EB

Udachin, KA

Enright, GD

Ratcliffe, CI

Ripmeester, JA

机构：

[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

[2] Carleton Univ, Ottawa Carleton Chem Inst, Ottawa, ON K1S 5B6, Canada

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 05期

关键词：

D O I：

10.1039/a705508k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five-membered aliphatic guests X(CH2)(3)Y (X, Y = Me, OH, Cl, Br) adopt equilibrium positions in the asymmetric p-tert-butylcalix[4]arene cavity formed in the solid state and reveal a marked aversion of the host pocket for halogen end-groups.

引用

页码：587 / 588

页数：2

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