Copper in Photocatalysis

被引：243
作者：
Paria, Suva [1 ]
Reiser, Oliver [1 ]
机构：
[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany
来源：
CHEMCATCHEM | 2014年 / 6卷 / 09期
关键词：
CC coupling; copper; ligand effects; photochemistry; radical reactions; METAL-FREE SYSTEM; PHOTOREDOX CATALYSIS; C-C; DIARYLIODONIUM SALTS; VALENCE ISOMERIZATION; HYDROGEN-PRODUCTION; ELECTRON-TRANSFER; COUPLING REACTION; ROOM-TEMPERATURE; ENERGY-TRANSFER;
D O I：
10.1002/cctc.201402237
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Light-induced electron transfer (Cu-I to Cu-II), oxidative addition (Cu-I to Cu-III), or the activation of copper alkene or alkyne complexes are possible key steps that offer unique possibilities for organic synthesis, including [2+2]-cycloadditions, cross-coupling reactions or atom transfer radical additions. This Minireview provides an overview on the photophysical properties of photocatalysts based on copper and on synthetic transformations mediated by them.
引用
收藏
页码：2477 / 2483
页数：7
相关论文
共 77 条
  • [1] STUDIES OF PHOTOINDUCED ELECTRON-TRANSFER FROM BIS(2,9-DIMETHYL-1-1,10-PHENANTHROLINE)COPPER(I)
    AHN, BT
    MCMILLIN, DR
    [J]. INORGANIC CHEMISTRY, 1978, 17 (08) : 2253 - 2258
  • [2] SPECTRAL SENSITIZATION OF LARGE-BAND-GAP SEMICONDUCTORS (THIN-FILMS AND CERAMICS) BY A CARBOXYLATED BIS(1,10-PHENANTHROLINE)COPPER(I) COMPLEX
    ALONSOVANTE, N
    NIERENGARTEN, JF
    SAUVAGE, JP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (11): : 1649 - 1654
  • [3] [Anonymous], 2013, ANGEW CHEM
  • [4] [Anonymous], 2005, ANGEW CHEM
  • [5] Photoactive mono- and polynuclear Cu(I)-phenanthrolines. A viable alternative to Ru(II)-polypyridines?
    Armaroli, N
    [J]. CHEMICAL SOCIETY REVIEWS, 2001, 30 (02) : 113 - 124
  • [6] Highly luminescent CuI complexes for light-emitting electrochemical cells
    Armaroli, Nicola
    Accorsi, Gianluca
    Holler, Michel
    Moudam, Omar
    Nierengarten, Jean-Francois
    Zhou, Zhongyuan
    Wegh, Rene T.
    Welter, Richard
    [J]. ADVANCED MATERIALS, 2006, 18 (10) : 1313 - 1316
  • [7] Bach T, 1998, SYNTHESIS-STUTTGART, P683
  • [8] Photoinitiated ambient temperature copper-catalyzed atom transfer radical addition (ATRA) and cyclization (ATRC) reactions in the presence of free-radical diazo initiator (AIBN)
    Balili, Marielle Nicole C.
    Pintauer, Tomislav
    [J]. DALTON TRANSACTIONS, 2011, 40 (12) : 3060 - 3066
  • [9] Intramolecular [2+2] photocycloaddition of alkenes incorporated in a carbohydrate template. Synthesis of enantiopure bicyclo[3.2.0]heptanes and -[6.3.0]undecanes
    Banerjee, S
    Ghosh, S
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (10) : 3981 - 3989
  • [10] Aryl Radical Formation by Copper(I) Photocatalyzed Reduction of Diaryliodonium Salts: NMR Evidence for a CuII/CuI Mechanism
    Baralle, Alexandre
    Fensterbank, Louis
    Goddard, Jean-Philippe
    Ollivier, Cyril
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (33) : 10809 - 10813
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