Photocatalyzed cross-dehydrogenative coupling of silanes with alcohols and water

被引：38

作者：

Lv, Haiping ^{[1
]}

Laishram, Ronibala Devi ^{[1
]}

Chen, Jingchao ^{[1
]}

Khan, Ruhima ^{[1
]}

Zhu, Yuanbin ^{[2
]}

Wu, Shiyuan ^{[2
]}

Zhang, Jianqiang ^{[3
]}

Liu, Xingyuan ^{[3
]}

Fan, Baomin ^{[1
]}

机构：

[1] Yunnan Minzu Univ, Key Lab Chem Ethn Med Resources, Yuehua St, Kunming 650500, Yunnan, Peoples R China

[2] Yunnan Tiefeng High Tech Min Chem Co Ltd, Qingfeng Ind Pk, Lufeng 651200, Yunnan, Peoples R China

[3] Puer Univ, Coll Biol & Chem, Puer 665000, Yunnan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 30期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1039/d1cc00129a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient method for the dehydrogenative coupling of silanes with alcohols under photocatalysis was developed. The reaction proceeded in the presence of Ru(bpy)(3)Cl-2 (0.5 mol%) under visible light irradiation in acetonitrile at room temperature. The developed methodology was also applicable for the synthesis of silanols using water as a coupling partner.

引用

收藏

页码：3660 / 3663

页数：4

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