Vortex-Assisted Dispersive Micro-Solid Phase Extraction Using CTAB-Modified Zeolite NaY Sorbent Coupled with HPLC for the Determination of Carbamate Insecticides

被引:74
作者
Salisaeng, Pawina [1 ,2 ]
Arnnok, Prapha [1 ,2 ]
Patdhanagul, Nopbhasinthu [3 ,4 ]
Burakham, Rodjana [1 ,2 ]
机构
[1] Khon Kaen Univ, Mat Chem Res Ctr, Dept Chem, Fac Sci, Khon Kaen 40002, Thailand
[2] Khon Kaen Univ, Ctr Innovat Chem, Fac Sci, Khon Kaen 40002, Thailand
[3] Kasetsart Univ, Ctr Adv Studies Ind Technol, Bangkok 10900, Thailand
[4] Kasetsart Univ, Dept Gen Sci, Fac Sci & Engn, Chalermphrakiat Sakon Nakhon Prov Campus, Sakon Nakhon 47000, Thailand
关键词
dispersive micro-solid phase extraction; zeolite; surfactant; carbamate; HPLC; PERFORMANCE LIQUID-CHROMATOGRAPHY; ENHANCED EMULSIFICATION MICROEXTRACTION; ENVIRONMENTAL WATER; MASS-SPECTROMETRY; HOLLOW SPHERES; PRECONCENTRATION; RESIDUES; PESTICIDES; SAMPLES; NANOPARTICLES;
D O I
10.1021/acs.jafc.5b05437
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
A vortex-assisted dispersive micro-solid phase extraction (VA-D-mu-SPE) based on cetyltrimethylammonium bromide (CTAB)-modified zeolite NaY was developed for preconcentration of carbamate pesticides in fruits, vegetables, and natural surface water prior to analysis by high performance liquid chromatography with photodiode array detection. The small amounts of solid sorbent were dispersed in a sample solution, and extraction occurred by adsorption in a short time, which was accelerated by vortex agitation. Finally, the sorbents were filtered from the solution, and the analytes were subsequently desorbed using an appropriate solvent. Parameters affecting the VA-D-mu-SPE performance including sorbent amount, sample volume, desorption solvent,and vortex time were optimized. Under the optimum condition, linear dynamic ranges were achieved between 0.004-24.000 mg kg(-1) (R-2 > 0.9946). The limits of detection (LODs) ranged from 0.004-4.000 mg kg(-1). The applicability of the developed procedure was successfully evaluated by the determination of the carbamate residues in fruits (dragon fruit, rambutan, and watermelon), vegetables (cabbage, cauliflower, and cucumber), and natural surface water.
引用
收藏
页码:2145 / 2152
页数:8
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